(eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand

S.B. Jensen, M.D. Spicer

Research output: Contribution to journalArticle

Abstract

The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.
Original languageEnglish
Pages (from-to)o978-o979
JournalActa Crystallographica Section E: Structure Reports
Volume57
Issue number10
DOIs
Publication statusPublished - Oct 2001

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Ruthenium
Benzene
Phosphorus
ruthenium
phosphorus
Chlorides
chlorides
Ligands
benzene
ligands
Molecules
molecules

Keywords

  • crystallography
  • [(η6-C6H6){PhP(CH2CH=CH2)2}RuCl2]
  • diallylphosphine ligand
  • ruthenium(ii)

Cite this

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abstract = "The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.",
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T1 - (eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand

AU - Jensen, S.B.

AU - Spicer, M.D.

PY - 2001/10

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N2 - The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.

AB - The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.

KW - crystallography

KW - [(η6-C6H6){PhP(CH2CH=CH2)2}RuCl2]

KW - diallylphosphine ligand

KW - ruthenium(ii)

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UR - http://dx.doi.org/10.1107/S1600536801015215

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M3 - Article

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JF - Acta Crystallographica Section E: Structure Reports

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