TY - JOUR
T1 - (eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand
AU - Jensen, S.B.
AU - Spicer, M.D.
PY - 2001/10
Y1 - 2001/10
N2 - The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.
AB - The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.
KW - crystallography
KW - [(η6-C6H6){PhP(CH2CH=CH2)2}RuCl2]
KW - diallylphosphine ligand
KW - ruthenium(ii)
UR - http://www.blackwell-synergy.com/doi/full/10.1107/S1600536801015215
UR - http://dx.doi.org/10.1107/S1600536801015215
U2 - 10.1107/S1600536801015215
DO - 10.1107/S1600536801015215
M3 - Article
SN - 1600-5368
VL - 57
SP - o978-o979
JO - Acta Crystallographica Section E: Structure Reports
JF - Acta Crystallographica Section E: Structure Reports
IS - 10
ER -