### Abstract

Original language | English |
---|---|

Pages (from-to) | 3442-3449 |

Number of pages | 8 |

Journal | Journal of Chemical Physics |

Volume | 112 |

Issue number | 7 |

DOIs | |

Publication status | Published - 15 Feb 2000 |

### Fingerprint

### Keywords

- 2nd virial-coefficient
- monte-carlo calculation
- hard-sphere chains
- critical exponents
- intramolecular structures
- chemical-equilibria
- field-theory
- molecules
- simulation
- fluids

### Cite this

*Journal of Chemical Physics*,

*112*(7), 3442-3449. https://doi.org/10.1063/1.480501

}

*Journal of Chemical Physics*, vol. 112, no. 7, pp. 3442-3449. https://doi.org/10.1063/1.480501

**Equation of state for polymer chains in good solvents.** / Lue, L.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Equation of state for polymer chains in good solvents

AU - Lue, L.

N1 - English Article 280HW J CHEM PHYS

PY - 2000/2/15

Y1 - 2000/2/15

N2 - A free-energy model is developed for polymer chains in good solvents.This model, which combines the ideas of polymer field theory with liquid-state theory, is valid in the dilute, semidilute, and concentrated regimes. The model is compared against computer simulation data for the equation of state of tangent hard-sphere chain fluids. At low concentrations, it accurately describes the thermodynamics of tangent hard-sphere chains, reproducing the universal scaling behavior of long chains. At high concentrations, the model has an accuracy comparable to those of previous equations of state for tangent hard-sphere chains.[S0021-9606(00)51407-X].

AB - A free-energy model is developed for polymer chains in good solvents.This model, which combines the ideas of polymer field theory with liquid-state theory, is valid in the dilute, semidilute, and concentrated regimes. The model is compared against computer simulation data for the equation of state of tangent hard-sphere chain fluids. At low concentrations, it accurately describes the thermodynamics of tangent hard-sphere chains, reproducing the universal scaling behavior of long chains. At high concentrations, the model has an accuracy comparable to those of previous equations of state for tangent hard-sphere chains.[S0021-9606(00)51407-X].

KW - 2nd virial-coefficient

KW - monte-carlo calculation

KW - hard-sphere chains

KW - critical exponents

KW - intramolecular structures

KW - chemical-equilibria

KW - field-theory

KW - molecules

KW - simulation

KW - fluids

UR - http://jcp.aip.org/resource/1/jcpsa6/v112/i7/p3442_s1?isAuthorized=no

U2 - 10.1063/1.480501

DO - 10.1063/1.480501

M3 - Article

VL - 112

SP - 3442

EP - 3449

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 7

ER -