Enhanced UV-light driven photocatalytic performance of magnetic CoFe₂O₄/TiO₂ nanohybrid for environmental applications

In this work, CoFe₂O₄/TiO₂ nanostructure was prepared through a facile and effective solvothermal route for efficient use in the degradation of the Erionyl Red A-3G model pollutant under ultraviolet irradiation. Characterization analysis indicated the successful heterojunction among the precursors. The composite presented band gap value of 2.75 eV, being smaller than that of the pristine TiO₂, as well as mesoporous structure. The catalytic activity of nanostructure was investigated by employing a 2² factorial experimental design with 3 central points. The optimized reaction conditions were set as pH = 2 and catalyst dosage = 1.0 g L^-1 for an initial pollutant concentration of 20 mg L^-1. The prepared nanohybrid presented remarkable catalytic activity, reaching color removal efficiency of 95.39% after 15 min, as well as total organic carbon (TOC) removal of 69.4% after 120 min. The kinetic studies of TOC removal followed the pseudo-first order model, with a rate constant of 0.10 min^-1. Moreover, the nanostructure presented magnetic behavior, being easily separated from the aqueous medium through the use of a simple external magnetic field.