Electromagnetic susceptibility anisotropy and its importance for paramagnetic NMR and optical spectroscopy in lanthanide coordination chemistry

Octavia A. Blackburn, Robert M. Edkins, Stephen Faulkner, Alan M. Kenwright, David Parker, Nicola J. Rogers, Sergey Shuvaev

Research output: Contribution to journalReview article

38 Citations (Scopus)

Abstract

The importance of the directional dependence of magnetic susceptibility in magnetic resonance and of electric susceptibility in the optical spectroscopy of lanthanide coordination complexes is assessed. A body of more reliable shift, relaxation and optical emission data is emerging for well-defined isostructural series of complexes, allowing detailed comparative analyses to be undertaken. Such work is highlighting the limitations of the current NMR shift and relaxation theories, as well as emphasising the absence of a compelling theoretical framework to explain optical emission phenomena.

LanguageEnglish
Pages6782-6800
Number of pages19
JournalDalton Transactions
Volume45
Issue number16
DOIs
Publication statusPublished - 28 Apr 2016

Fingerprint

Lanthanoid Series Elements
Coordination Complexes
Magnetic resonance
Magnetic susceptibility
Nuclear magnetic resonance spectroscopy
Anisotropy
Nuclear magnetic resonance
Optical spectroscopy

Keywords

  • electromagnetic susceptibility
  • anisotropy
  • NMR
  • optical spectroscopy
  • lanthanide coordination chemistry

Cite this

Blackburn, Octavia A. ; Edkins, Robert M. ; Faulkner, Stephen ; Kenwright, Alan M. ; Parker, David ; Rogers, Nicola J. ; Shuvaev, Sergey. / Electromagnetic susceptibility anisotropy and its importance for paramagnetic NMR and optical spectroscopy in lanthanide coordination chemistry. In: Dalton Transactions. 2016 ; Vol. 45, No. 16. pp. 6782-6800.
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Electromagnetic susceptibility anisotropy and its importance for paramagnetic NMR and optical spectroscopy in lanthanide coordination chemistry. / Blackburn, Octavia A.; Edkins, Robert M.; Faulkner, Stephen; Kenwright, Alan M.; Parker, David; Rogers, Nicola J.; Shuvaev, Sergey.

In: Dalton Transactions, Vol. 45, No. 16, 28.04.2016, p. 6782-6800.

Research output: Contribution to journalReview article

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