Abstract
Efficient conversion of ketones into kinetic enol phosphates under mild and accessible conditions has been realised using the developed methods with di-tert-butylmagnesium and bismesitylmagnesium. Optimisation of the quench protocol resulted in high yields of enol phosphates from a range of cyclohexanones and aryl methyl ketones, with tolerance of a range of additional functional units.
Original language | English |
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Pages (from-to) | 10131-10135 |
Number of pages | 5 |
Journal | Organic and Biomolecular Chemistry |
Volume | 13 |
Issue number | 40 |
DOIs | |
Publication status | Published - 21 Sept 2015 |
Keywords
- ketones
- kinetic enol phosphates
- cyclohexanones