Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 598-600 |
| Number of pages | 2 |
| Journal | Chemical Communications (London) |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 2007 |
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Keywords
- chemistry
- magnesium
- reagents
- dizincation
- dimagnesiation
- zinc
- metallation
- alkali-metal-mediated metallation
- benzene
Cite this
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Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation. / Armstrong, D.R.; Clegg, William; Dale, S.H.; Graham, D.V.; Hevia, E.; Hogg, L.M.; Honeyman, G.W.; Kennedy, A.R.; Mulvey, R.E.
In: Chemical Communications (London), No. 6, 2007, p. 598-600.Research output: Contribution to journal › Article
TY - JOUR
T1 - Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation
AU - Armstrong, D.R.
AU - Clegg, William
AU - Dale, S.H.
AU - Graham, D.V.
AU - Hevia, E.
AU - Hogg, L.M.
AU - Honeyman, G.W.
AU - Kennedy, A.R.
AU - Mulvey, R.E.
N1 - Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record.
PY - 2007
Y1 - 2007
N2 - Benzene can be easily 1,4-dideprotonated stoichiometrically on reaction with two equivalents of a synergic mixture of tBu2Zn, NaTMP and TMEDA to give a unique 1,4-dizincated benzene product which has been characterised by X-ray crystallography and NMR spectroscopy as well as modelled theoretically by DFT computational studies; a related synergic dimagnesiation of benzene is also reported.
AB - Benzene can be easily 1,4-dideprotonated stoichiometrically on reaction with two equivalents of a synergic mixture of tBu2Zn, NaTMP and TMEDA to give a unique 1,4-dizincated benzene product which has been characterised by X-ray crystallography and NMR spectroscopy as well as modelled theoretically by DFT computational studies; a related synergic dimagnesiation of benzene is also reported.
KW - chemistry
KW - magnesium
KW - reagents
KW - dizincation
KW - dimagnesiation
KW - zinc
KW - metallation
KW - alkali-metal-mediated metallation
KW - benzene
UR - http://dx.doi.org/10.1039/b613655a
U2 - 10.1039/b613655a
DO - 10.1039/b613655a
M3 - Article
SP - 598
EP - 600
JO - Chemical Communications (London)
JF - Chemical Communications (London)
SN - 0009-241X
IS - 6
ER -