Diverse outcomes of CO2 fixation using alkali metal amides including formation of a heterobimetallic lithium-sodium carbamato-anhydride via lithium-sodium bis-hexamethyldisilazide

Richard M. Gauld, Alan R. Kennedy, Ross McLellan, Jim Barker, Jacqueline Reid, Robert E. Mulvey

Research output: Contribution to journalArticle

3 Citations (Scopus)
10 Downloads (Pure)

Abstract

Fixation of CO2 by lithium amides derived from pyrrole and diisopropylamine generates a lithium carbamate polymer and dodecamer respectively. Moving to lithium-sodium hexamethyldisilazide produces a more complicated, intriguing reaction, where unusually the bimetallic composition is maintained in the product but its composition contains both carbamato and anhydride functionalities.
Original languageEnglish
Pages (from-to)1478-1481
Number of pages4
JournalChemical Communications
Volume55
Issue number10
Early online date15 Jan 2019
DOIs
Publication statusPublished - 29 Jan 2019

Keywords

  • CO2 fixation
  • metal amides
  • lithium carbamate polymers

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