Directed synthesis of {CuII2ZnII2} and {CuII8ZnII8} heterometallic complexes

María José Heras Ojea; Claire Wilson; Simon J. Coles; Floriana Tuna; Mark Murrie

doi:10.1039/c5dt03344f

Directed synthesis of {CuII2ZnII2} and {CuII8ZnII8} heterometallic complexes

María José Heras Ojea, Claire Wilson, Simon J. Coles, Floriana Tuna, Mark Murrie

Strathclyde Institute Of Pharmacy And Biomedical Sciences

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Abstract

The polydentate ligand Bis–tris propane is used to assemble two Cu/Zn heterometallic complexes: a tetramer which displays an unusually strong Cu(ii)⋯Cu(ii) exchange given the Cu⋯Cu separation or, in the presence of base, a hexadecanuclear complex with a remarkable double-concentric ring structure.

Original language	English
Pages (from-to)	19275-19281
Number of pages	7
Journal	Dalton Transactions
Early online date	14 Oct 2015
DOIs	https://doi.org/10.1039/c5dt03344f
Publication status	Published - 28 Nov 2015

Keywords

heterometallic complexes
synthesis
Cu(II) ions

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10.1039/c5dt03344fLicence: CC BY 3.0

Ojea-etal-DT-2015-Directed-synthesis-of-CuII2ZnII2-and-CuII8ZnII8Final published version, 729 KBLicence: CC BY 3.0

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title = "Directed synthesis of {CuII2ZnII2} and {CuII8ZnII8} heterometallic complexes",

abstract = "The polydentate ligand Bis–tris propane is used to assemble two Cu/Zn heterometallic complexes: a tetramer which displays an unusually strong Cu(ii)⋯Cu(ii) exchange given the Cu⋯Cu separation or, in the presence of base, a hexadecanuclear complex with a remarkable double-concentric ring structure.",

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doi = "10.1039/c5dt03344f",

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T1 - Directed synthesis of {CuII2ZnII2} and {CuII8ZnII8} heterometallic complexes

AU - Ojea, María José Heras

AU - Wilson, Claire

AU - Coles, Simon J.

AU - Tuna, Floriana

AU - Murrie, Mark

PY - 2015/11/28

Y1 - 2015/11/28

N2 - The polydentate ligand Bis–tris propane is used to assemble two Cu/Zn heterometallic complexes: a tetramer which displays an unusually strong Cu(ii)⋯Cu(ii) exchange given the Cu⋯Cu separation or, in the presence of base, a hexadecanuclear complex with a remarkable double-concentric ring structure.

AB - The polydentate ligand Bis–tris propane is used to assemble two Cu/Zn heterometallic complexes: a tetramer which displays an unusually strong Cu(ii)⋯Cu(ii) exchange given the Cu⋯Cu separation or, in the presence of base, a hexadecanuclear complex with a remarkable double-concentric ring structure.

KW - heterometallic complexes

KW - synthesis

KW - Cu(II) ions

U2 - 10.1039/c5dt03344f

DO - 10.1039/c5dt03344f

M3 - Article

SN - 1477-9226

SP - 19275

EP - 19281

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Directed synthesis of {CuII2ZnII2} and {CuII8ZnII8} heterometallic complexes

Abstract

Keywords

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