Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs. Si-O bond cleavage

E. Hevia, A.R. Kennedy, J. Klett, M.D. McCall

Research output: Contribution to journalArticle

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Abstract

A new application of zincate [(THF) Li(TMP)(Bu-t) Zn(Bu-t)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DIZn) of trimethyl(phenoxy) silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.
Original languageEnglish
Pages (from-to)3240-3242
Number of pages2
JournalChemical Communications (London)
Issue number22
DOIs
Publication statusPublished - 2009

Keywords

  • tertiary aromatic amide
  • structural insights
  • TMP-Zincate
  • chemistry

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