Abstract
A new application of zincate [(THF) Li(TMP)(Bu-t) Zn(Bu-t)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DIZn) of trimethyl(phenoxy) silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.
Original language | English |
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Pages (from-to) | 3240-3242 |
Number of pages | 2 |
Journal | Chemical Communications (London) |
Issue number | 22 |
DOIs | |
Publication status | Published - 2009 |
Keywords
- tertiary aromatic amide
- structural insights
- TMP-Zincate
- chemistry