Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs. Si-O bond cleavage

E. Hevia, A.R. Kennedy, J. Klett, M.D. McCall

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A new application of zincate [(THF) Li(TMP)(Bu-t) Zn(Bu-t)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DIZn) of trimethyl(phenoxy) silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.
LanguageEnglish
Pages3240-3242
Number of pages2
JournalChemical Communications (London)
Issue number22
DOIs
Publication statusPublished - 2009

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Thymidine Monophosphate
Alkali Metals
Silanes

Keywords

  • tertiary aromatic amide
  • structural insights
  • TMP-Zincate
  • chemistry

Cite this

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abstract = "A new application of zincate [(THF) Li(TMP)(Bu-t) Zn(Bu-t)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DIZn) of trimethyl(phenoxy) silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.",
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Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC-H vs. Si-O bond cleavage. / Hevia, E.; Kennedy, A.R.; Klett, J.; McCall, M.D.

In: Chemical Communications (London), No. 22, 2009, p. 3240-3242.

Research output: Contribution to journalArticle

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AU - Hevia, E.

AU - Kennedy, A.R.

AU - Klett, J.

AU - McCall, M.D.

PY - 2009

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AB - A new application of zincate [(THF) Li(TMP)(Bu-t) Zn(Bu-t)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DIZn) of trimethyl(phenoxy) silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.

KW - tertiary aromatic amide

KW - structural insights

KW - TMP-Zincate

KW - chemistry

UR - http://dx.doi.org/10.1039/b903592c

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DO - 10.1039/b903592c

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SN - 0009-241X

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