Diphenylzirconocene

W  Clegg; L  Horsburgh; D M  Lindsay; Robert Mulvey

doi:10.1107/S0108270197019343

Diphenylzirconocene

W Clegg, L Horsburgh, D M Lindsay, Robert Mulvey

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The title compound, [Zr(C5H5)(2)(C6H5)(2)], has two cyclopentadienyl and two phenyl ligands arranged in a distorted tetrahedral geometry around the Zr atom, Steric interactions produce an opening of the Cp-Zr-Cp angle to 131.7(1) degrees and a tilting of both phenyl rings in their own planes about the Zr-C bonds by several degrees.

Original language	English
Pages (from-to)	315-317
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
DOIs	https://doi.org/10.1107/S0108270197019343
Publication status	Published - 15 Mar 1998

Keywords

diphenylzirconocene
tetrahedral geometry

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10.1107/S0108270197019343

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title = "Diphenylzirconocene",

abstract = "The title compound, [Zr(C5H5)(2)(C6H5)(2)], has two cyclopentadienyl and two phenyl ligands arranged in a distorted tetrahedral geometry around the Zr atom, Steric interactions produce an opening of the Cp-Zr-Cp angle to 131.7(1) degrees and a tilting of both phenyl rings in their own planes about the Zr-C bonds by several degrees.",

keywords = "diphenylzirconocene, tetrahedral geometry",

author = "W Clegg and L Horsburgh and Lindsay, {D M} and Robert Mulvey",

year = "1998",

month = mar,

day = "15",

doi = "10.1107/S0108270197019343",

language = "English",

volume = "54",

pages = "315--317",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

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TY - JOUR

T1 - Diphenylzirconocene

AU - Clegg, W

AU - Horsburgh, L

AU - Lindsay, D M

AU - Mulvey, Robert

PY - 1998/3/15

Y1 - 1998/3/15

N2 - The title compound, [Zr(C5H5)(2)(C6H5)(2)], has two cyclopentadienyl and two phenyl ligands arranged in a distorted tetrahedral geometry around the Zr atom, Steric interactions produce an opening of the Cp-Zr-Cp angle to 131.7(1) degrees and a tilting of both phenyl rings in their own planes about the Zr-C bonds by several degrees.

AB - The title compound, [Zr(C5H5)(2)(C6H5)(2)], has two cyclopentadienyl and two phenyl ligands arranged in a distorted tetrahedral geometry around the Zr atom, Steric interactions produce an opening of the Cp-Zr-Cp angle to 131.7(1) degrees and a tilting of both phenyl rings in their own planes about the Zr-C bonds by several degrees.

KW - diphenylzirconocene

KW - tetrahedral geometry

U2 - 10.1107/S0108270197019343

DO - 10.1107/S0108270197019343

M3 - Article

VL - 54

SP - 315

EP - 317

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

ER -

Diphenylzirconocene

Abstract

Keywords

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