Diphenylzirconocene

W Clegg, L Horsburgh, D M Lindsay, Robert Mulvey

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The title compound, [Zr(C5H5)(2)(C6H5)(2)], has two cyclopentadienyl and two phenyl ligands arranged in a distorted tetrahedral geometry around the Zr atom, Steric interactions produce an opening of the Cp-Zr-Cp angle to 131.7(1) degrees and a tilting of both phenyl rings in their own planes about the Zr-C bonds by several degrees.

LanguageEnglish
Pages315-317
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
DOIs
Publication statusPublished - 15 Mar 1998

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Ligands
Atoms
Geometry

Keywords

  • diphenylzirconocene
  • tetrahedral geometry

Cite this

Clegg, W ; Horsburgh, L ; Lindsay, D M ; Mulvey, Robert. / Diphenylzirconocene. In: Acta Crystallographica Section C: Crystal Structure Communications. 1998 ; Vol. 54. pp. 315-317.
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Diphenylzirconocene. / Clegg, W ; Horsburgh, L ; Lindsay, D M ; Mulvey, Robert.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 54, 15.03.1998, p. 315-317.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Diphenylzirconocene

AU - Clegg, W

AU - Horsburgh, L

AU - Lindsay, D M

AU - Mulvey, Robert

PY - 1998/3/15

Y1 - 1998/3/15

N2 - The title compound, [Zr(C5H5)(2)(C6H5)(2)], has two cyclopentadienyl and two phenyl ligands arranged in a distorted tetrahedral geometry around the Zr atom, Steric interactions produce an opening of the Cp-Zr-Cp angle to 131.7(1) degrees and a tilting of both phenyl rings in their own planes about the Zr-C bonds by several degrees.

AB - The title compound, [Zr(C5H5)(2)(C6H5)(2)], has two cyclopentadienyl and two phenyl ligands arranged in a distorted tetrahedral geometry around the Zr atom, Steric interactions produce an opening of the Cp-Zr-Cp angle to 131.7(1) degrees and a tilting of both phenyl rings in their own planes about the Zr-C bonds by several degrees.

KW - diphenylzirconocene

KW - tetrahedral geometry

U2 - 10.1107/S0108270197019343

DO - 10.1107/S0108270197019343

M3 - Article

VL - 54

SP - 315

EP - 317

JO - Acta Crystallographica Section C: Crystal Structure Communications

T2 - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

ER -