Abstract
| Language | English |
|---|---|
| Pages | 3185–3188 |
| Number of pages | 4 |
| Journal | Angewandte Chemie International Edition |
| Volume | 49 |
| Issue number | 18 |
| Early online date | 29 Mar 2010 |
| DOIs | |
| Publication status | Published - 19 Apr 2010 |
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Keywords
- amides
- grignard reagents
- metalation
- structure elucidation
- DOSY NMR spectroscopy
Cite this
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Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities. / Armstrong, David R.; Garcia-Álvarez, Pablo; Kennedy, Alan R.; Mulvey, Robert E.; Parkinson, John A.
In: Angewandte Chemie International Edition , Vol. 49, No. 18, 19.04.2010, p. 3185–3188.Research output: Contribution to journal › Article
TY - JOUR
T1 - Diisopropylamide and TMP turbo-grignard reagents
T2 - Angewandte Chemie International Edition
AU - Armstrong, David R.
AU - Garcia-Álvarez, Pablo
AU - Kennedy, Alan R.
AU - Mulvey, Robert E.
AU - Parkinson, John A.
N1 - This is the peer reviewed version of the following article: Armstrong, DR, Garcia-Álvarez, P, Kennedy, AR, Mulvey, RE & Parkinson, JA 2010, 'Diisopropylamide and TMP turbo-grignard reagents: a structural rationale for their contrasting reactivities' Angewandte Chemie International Edition , vol 49, no. 18, pp. 3185–3188, which has been published in final form at https://doi.org/10.1002/anie.201000539. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
PY - 2010/4/19
Y1 - 2010/4/19
N2 - A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent "(iPr2N)MgCl⋅LiCl" (see structure; blue N, red O, green Mg, yellow Cl, black C) separates into several charged ate species in dynamic exchange with each other in THF solution as determined by a combination of EXSY and DOSY NMR studies.
AB - A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent "(iPr2N)MgCl⋅LiCl" (see structure; blue N, red O, green Mg, yellow Cl, black C) separates into several charged ate species in dynamic exchange with each other in THF solution as determined by a combination of EXSY and DOSY NMR studies.
KW - amides
KW - grignard reagents
KW - metalation
KW - structure elucidation
KW - DOSY NMR spectroscopy
UR - http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3773
U2 - 10.1002/anie.201000539
DO - 10.1002/anie.201000539
M3 - Article
VL - 49
SP - 3185
EP - 3188
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 18
ER -