Diffraction gratings for chiral molecules and their applications

Robert P. Cameron, Alison Yao, Stephen M. Barnett

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

We suggest the use of certain readily producible types of light to exert a force that points in opposite directions for the enantiomers of a chiral molecule and propose multiple devices based upon this novel manifestation of optical activity: in particular, our discriminatory chiral diffraction grating; a device that could be employed, for example, to measure the enantiomeric excess of a sample of chiral molecules simply and to high precision. Our work is relevant for many types of molecules and our proposed devices may be realizable using currently existing technology.
Original languageEnglish
Pages (from-to)3472-3478
Number of pages7
JournalJournal of Physical Chemistry A
Volume118
Issue number19
DOIs
Publication statusPublished - 15 May 2014

Keywords

  • chiral molecule
  • optical activity
  • chiral diffraction grating

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