Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] (R=H or Me): N-H vs. Re-N

E  Hevia; J  Perez; V  Riera; D  Miguel

doi:10.1039/b203261a

Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] (R=H or Me): N-H vs. Re-N

E Hevia, J Perez, V Riera, D Miguel

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The reactions of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] complexes lead to R NCO insertion into the Re-N bond (for R = Me) or the N-H bond (R = H).

Original language	English
Pages (from-to)	1814-1815
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b203261a
Publication status	Published - 2002

Keywords

aryloxide complexes
oxygen bonds
rhenium
amido
alkoxide
metals

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10.1039/b203261a

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@article{2f030a9184724b14bc0c5c7e1639180f,

title = "Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] (R=H or Me): N-H vs. Re-N",

abstract = "The reactions of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] complexes lead to R NCO insertion into the Re-N bond (for R = Me) or the N-H bond (R = H).",

keywords = "aryloxide complexes, oxygen bonds, rhenium, amido, alkoxide, metals",

author = "E Hevia and J Perez and V Riera and D Miguel",

year = "2002",

doi = "10.1039/b203261a",

language = "English",

pages = "1814--1815",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

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TY - JOUR

T1 - Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] (R=H or Me): N-H vs. Re-N

AU - Hevia, E

AU - Perez, J

AU - Riera, V

AU - Miguel, D

PY - 2002

Y1 - 2002

N2 - The reactions of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] complexes lead to R NCO insertion into the Re-N bond (for R = Me) or the N-H bond (R = H).

AB - The reactions of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] complexes lead to R NCO insertion into the Re-N bond (for R = Me) or the N-H bond (R = H).

KW - aryloxide complexes

KW - oxygen bonds

KW - rhenium

KW - amido

KW - alkoxide

KW - metals

U2 - 10.1039/b203261a

DO - 10.1039/b203261a

M3 - Article

SN - 1359-7345

SP - 1814

EP - 1815

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] (R=H or Me): N-H vs. Re-N

Abstract

Keywords

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