The reactions of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] complexes lead to R NCO insertion into the Re-N bond (for R = Me) or the N-H bond (R = H).
- aryloxide complexes
- oxygen bonds
Hevia, E., Perez, J., Riera, V., & Miguel, D. (2002). Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] (R=H or Me): N-H vs. Re-N. Chemical Communications, (17), 1814-1815. https://doi.org/10.1039/b203261a