Dichlorobis(triphenylphosphine oxide-?O)nickel(II)

R. Moreno-Fuquen, O. Cifuentes, J.V. Naranjo, L.M. Serratto, A.R. Kennedy

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title nickel(II) complex, [NiCl2(C18H15OP)2], was prepared in order to determine the coordination of the Ni atom. The Ni atom lies on a twofold axis and is four-coordinated by two Cl atoms and two O atoms in a distorted tetrahedral coordination geometry. The Ni - Cl and Ni - O distances are 2.2151 (6) and 1.9662 (16) î.., respectively. The title compound is compared with the four-coordinated copper(II) analog; the two systems are isostructural.
Original languageEnglish
Pages (from-to)1861-1862
Number of pages1
JournalActa Crystallographica Section E: Structure Reports
Volume60
Issue number12
DOIs
Publication statusPublished - 20 Nov 2004

Keywords

  • Ni atom
  • twofold axis
  • tetrahedral
  • compound
  • isostructural

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