Dibromo(diethylether-O)(diisopropylamine-N)magnesium(II)

K.W. Henderson, A.R. Kennedy

Research output: Contribution to journalArticle

Abstract

The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is shown to be distorted tetrahedral. The presence of a secondary amine ligand is unusual in its derivation from an amide. It is also unusual to find both an ether and a simple amine solvating the same magnesium centre [MgI--N 1 2.158 (3) and Mgl--O1 2.041 (3) A].
LanguageEnglish
Pages7816-7824
Number of pages8
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
Issue number9
DOIs
Publication statusPublished - 1998

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Amides
Ether
Magnesium
Ligands
Atoms
Geometry
diisopropylamine

Keywords

  • Mg atom
  • distorted tetrahedral
  • amine ligand
  • magnesium

Cite this

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abstract = "The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is shown to be distorted tetrahedral. The presence of a secondary amine ligand is unusual in its derivation from an amide. It is also unusual to find both an ether and a simple amine solvating the same magnesium centre [MgI--N 1 2.158 (3) and Mgl--O1 2.041 (3) A].",
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Dibromo(diethylether-O)(diisopropylamine-N)magnesium(II). / Henderson, K.W.; Kennedy, A.R.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 54, No. 9, 1998, p. 7816-7824.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Dibromo(diethylether-O)(diisopropylamine-N)magnesium(II)

AU - Henderson, K.W.

AU - Kennedy, A.R.

PY - 1998

Y1 - 1998

N2 - The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is shown to be distorted tetrahedral. The presence of a secondary amine ligand is unusual in its derivation from an amide. It is also unusual to find both an ether and a simple amine solvating the same magnesium centre [MgI--N 1 2.158 (3) and Mgl--O1 2.041 (3) A].

AB - The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is shown to be distorted tetrahedral. The presence of a secondary amine ligand is unusual in its derivation from an amide. It is also unusual to find both an ether and a simple amine solvating the same magnesium centre [MgI--N 1 2.158 (3) and Mgl--O1 2.041 (3) A].

KW - Mg atom

KW - distorted tetrahedral

KW - amine ligand

KW - magnesium

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U2 - 10.1107/S0108270198003655

DO - 10.1107/S0108270198003655

M3 - Article

VL - 54

SP - 7816

EP - 7824

JO - Acta Crystallographica Section C: Crystal Structure Communications

T2 - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

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