Development and application of a polar coating for stir bar sorptive extraction of emerging pollutants from environmental water samples.

D. Bratkowska, R. M. Marce, P. A. G. Cormack, F. Borrull, N. Fontanals

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

In the present study, a stir bar coated with hydrophilic polymer based on poly(N-vinylpyrrolidone-co-divinylbenzene) was prepd. for the sorptive extn. of polar compds. The main parameters affecting the polymn. of the coating were investigated. The new stir bar was applied successfully in stir bar sorptive extn. with liq. desorption followed by liq. chromatog.-mass spectrometry in tandem with a triple quadrupole for the detn. of a group of polar pharmaceuticals and personal care products (PPCPs) in environmental water matrixes. Different variables affecting extn. and desorption such as agitation speed, temp., ionic strength and extn. time were optimized. The results showed that the stir bar is able to enrich the selected analytes effectively. The developed method was applied to det. a group of PPCPs in different complex environmental samples, including river, effluent and influent waste water.
LanguageEnglish
Pages135-142
Number of pages8
JournalAnalytica Chimica Acta
Volume706
Issue number1
DOIs
Publication statusPublished - 7 Nov 2011

Fingerprint

Water Pollutants
Environmental Pollutants
Pharmaceutical Services
divinyl benzene
coating
Coatings
pollutant
Water
Waste Water
Tandem Mass Spectrometry
Rivers
Osmolar Concentration
Desorption
desorption
Polymers
water
Ionic strength
Pharmaceutical Preparations
Mass spectrometry
Effluents

Keywords

  • stir bar sorptive extraction
  • monolithic polar material
  • pharmaceuticals and personal care products
  • environmental water samples
  • PPCPs
  • SBSE

Cite this

@article{745bb1f349134ada98c08ce645e35f9f,
title = "Development and application of a polar coating for stir bar sorptive extraction of emerging pollutants from environmental water samples.",
abstract = "In the present study, a stir bar coated with hydrophilic polymer based on poly(N-vinylpyrrolidone-co-divinylbenzene) was prepd. for the sorptive extn. of polar compds. The main parameters affecting the polymn. of the coating were investigated. The new stir bar was applied successfully in stir bar sorptive extn. with liq. desorption followed by liq. chromatog.-mass spectrometry in tandem with a triple quadrupole for the detn. of a group of polar pharmaceuticals and personal care products (PPCPs) in environmental water matrixes. Different variables affecting extn. and desorption such as agitation speed, temp., ionic strength and extn. time were optimized. The results showed that the stir bar is able to enrich the selected analytes effectively. The developed method was applied to det. a group of PPCPs in different complex environmental samples, including river, effluent and influent waste water.",
keywords = "stir bar sorptive extraction , monolithic polar material, pharmaceuticals and personal care products , environmental water samples, PPCPs, SBSE",
author = "D. Bratkowska and Marce, {R. M.} and Cormack, {P. A. G.} and F. Borrull and N. Fontanals",
year = "2011",
month = "11",
day = "7",
doi = "10.1016/j.aca.2011.08.028",
language = "English",
volume = "706",
pages = "135--142",
journal = "Analytica Chimica Acta",
issn = "0003-2670",
number = "1",

}

Development and application of a polar coating for stir bar sorptive extraction of emerging pollutants from environmental water samples. / Bratkowska, D.; Marce, R. M.; Cormack, P. A. G.; Borrull, F.; Fontanals, N.

In: Analytica Chimica Acta, Vol. 706, No. 1, 07.11.2011, p. 135-142.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Development and application of a polar coating for stir bar sorptive extraction of emerging pollutants from environmental water samples.

AU - Bratkowska, D.

AU - Marce, R. M.

AU - Cormack, P. A. G.

AU - Borrull, F.

AU - Fontanals, N.

PY - 2011/11/7

Y1 - 2011/11/7

N2 - In the present study, a stir bar coated with hydrophilic polymer based on poly(N-vinylpyrrolidone-co-divinylbenzene) was prepd. for the sorptive extn. of polar compds. The main parameters affecting the polymn. of the coating were investigated. The new stir bar was applied successfully in stir bar sorptive extn. with liq. desorption followed by liq. chromatog.-mass spectrometry in tandem with a triple quadrupole for the detn. of a group of polar pharmaceuticals and personal care products (PPCPs) in environmental water matrixes. Different variables affecting extn. and desorption such as agitation speed, temp., ionic strength and extn. time were optimized. The results showed that the stir bar is able to enrich the selected analytes effectively. The developed method was applied to det. a group of PPCPs in different complex environmental samples, including river, effluent and influent waste water.

AB - In the present study, a stir bar coated with hydrophilic polymer based on poly(N-vinylpyrrolidone-co-divinylbenzene) was prepd. for the sorptive extn. of polar compds. The main parameters affecting the polymn. of the coating were investigated. The new stir bar was applied successfully in stir bar sorptive extn. with liq. desorption followed by liq. chromatog.-mass spectrometry in tandem with a triple quadrupole for the detn. of a group of polar pharmaceuticals and personal care products (PPCPs) in environmental water matrixes. Different variables affecting extn. and desorption such as agitation speed, temp., ionic strength and extn. time were optimized. The results showed that the stir bar is able to enrich the selected analytes effectively. The developed method was applied to det. a group of PPCPs in different complex environmental samples, including river, effluent and influent waste water.

KW - stir bar sorptive extraction

KW - monolithic polar material

KW - pharmaceuticals and personal care products

KW - environmental water samples

KW - PPCPs

KW - SBSE

UR - http://www.scopus.com/inward/record.url?scp=80053637144&partnerID=8YFLogxK

U2 - 10.1016/j.aca.2011.08.028

DO - 10.1016/j.aca.2011.08.028

M3 - Article

VL - 706

SP - 135

EP - 142

JO - Analytica Chimica Acta

T2 - Analytica Chimica Acta

JF - Analytica Chimica Acta

SN - 0003-2670

IS - 1

ER -