Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

Alberto Hernan-Gomez; T.D. Bradley; A.R. Kennedy; Z. Livingstone; S.D. Robertson; E. Hevia

doi:10.1039/c3cc45167d

Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

Alberto Hernan-Gomez, T.D. Bradley, A.R. Kennedy, Z. Livingstone, S.D. Robertson, E. Hevia

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Mixed-metal reagents [NaMg(CHSiMe)] (1) and [(THF)NaMg(NPh)(THF)] [3-(THF)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.

Original language	English
Pages (from-to)	8659-8661
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	77
DOIs	https://doi.org/10.1039/c3cc45167d
Publication status	Published - 7 Oct 2013

Keywords

mixed-metal reagents
bimetallics
isocyanates

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10.1039/c3cc45167d

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abstract = "Mixed-metal reagents [NaMg(CHSiMe)] (1) and [(THF)NaMg(NPh)(THF)] [3-(THF)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.",

keywords = "mixed-metal reagents, bimetallics, isocyanates",

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AU - Bradley, T.D.

AU - Kennedy, A.R.

AU - Livingstone, Z.

AU - Robertson, S.D.

AU - Hevia, E.

PY - 2013/10/7

Y1 - 2013/10/7

N2 - Mixed-metal reagents [NaMg(CHSiMe)] (1) and [(THF)NaMg(NPh)(THF)] [3-(THF)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.

AB - Mixed-metal reagents [NaMg(CHSiMe)] (1) and [(THF)NaMg(NPh)(THF)] [3-(THF)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.

KW - mixed-metal reagents

KW - bimetallics

KW - isocyanates

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U2 - 10.1039/c3cc45167d

DO - 10.1039/c3cc45167d

M3 - Article

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Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

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Keywords

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Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

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