Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates

Alberto Hernan-Gomez, T.D. Bradley, A.R. Kennedy, Z. Livingstone, S.D. Robertson, E. Hevia

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Mixed-metal reagents [NaMg(CHSiMe)] (1) and [(THF)NaMg(NPh)(THF)] [3-(THF)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.
LanguageEnglish
Pages8659-8661
Number of pages3
JournalChemical Communications
Volume49
Issue number77
DOIs
Publication statusPublished - 7 Oct 2013

Fingerprint

Isocyanates
Metals
Sodium

Keywords

  • mixed-metal reagents
  • bimetallics
  • isocyanates

Cite this

@article{6ef87e6658be4f92b31c30f6a0a8fb27,
title = "Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates",
abstract = "Mixed-metal reagents [NaMg(CHSiMe)] (1) and [(THF)NaMg(NPh)(THF)] [3-(THF)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.",
keywords = "mixed-metal reagents, bimetallics, isocyanates",
author = "Alberto Hernan-Gomez and T.D. Bradley and A.R. Kennedy and Z. Livingstone and S.D. Robertson and E. Hevia",
year = "2013",
month = "10",
day = "7",
doi = "10.1039/c3cc45167d",
language = "English",
volume = "49",
pages = "8659--8661",
journal = "Chemical Communications",
issn = "1359-7345",
number = "77",

}

Developing catalytic applications of cooperative bimetallics : competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates . / Hernan-Gomez, Alberto; Bradley, T.D.; Kennedy, A.R.; Livingstone, Z.; Robertson, S.D.; Hevia, E.

In: Chemical Communications, Vol. 49, No. 77, 07.10.2013, p. 8659-8661.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Developing catalytic applications of cooperative bimetallics

T2 - Chemical Communications

AU - Hernan-Gomez, Alberto

AU - Bradley, T.D.

AU - Kennedy, A.R.

AU - Livingstone, Z.

AU - Robertson, S.D.

AU - Hevia, E.

PY - 2013/10/7

Y1 - 2013/10/7

N2 - Mixed-metal reagents [NaMg(CHSiMe)] (1) and [(THF)NaMg(NPh)(THF)] [3-(THF)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.

AB - Mixed-metal reagents [NaMg(CHSiMe)] (1) and [(THF)NaMg(NPh)(THF)] [3-(THF)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.

KW - mixed-metal reagents

KW - bimetallics

KW - isocyanates

UR - http://www.scopus.com/inward/record.url?scp=84883393825&partnerID=8YFLogxK

U2 - 10.1039/c3cc45167d

DO - 10.1039/c3cc45167d

M3 - Article

VL - 49

SP - 8659

EP - 8661

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 77

ER -