Demonstrator devices for artificial photosynthesis: general discussion

Ryu Abe; Catherine M. Aitchison; Virgil Andrei; Matthias Beller; Daniel Cheung; Charles E. Creissen; Víctor A. De La Peña O'Shea; James R. Durrant; Michael Grätzel; Leif Hammarström; Sophia Haussener; Su Il In; Evangelos Kalamaras; Akihiko Kudo; Moritz F. Kuehnel; Pramod Patil Kunturu; Yi Hsuan Lai; Chong Yong Lee; Marcelino Maneiro; Esther Edwardes Moore; Huu Chuong Nguyen; Aubrey R. Paris; Chanon Pornrungroj; Joost N.H. Reek; Erwin Reisner; Murielle Schreck; Wilson A. Smith; Han Sen Soo; Reiner Sebastian Sprick; Anirudh Venugopal; Qian Wang; Dominik Wielend; Martijn A. Zwijnenburg

doi:10.1039/C9FD90023C

Demonstrator devices for artificial photosynthesis: general discussion

Ryu Abe
, Catherine M. Aitchison
, Virgil Andrei
, Matthias Beller
, Daniel Cheung
, Charles E. Creissen
, Víctor A. De La Peña O'Shea
, James R. Durrant
, Michael Grätzel
, Leif Hammarström
, Sophia Haussener
, Su Il In
, Evangelos Kalamaras
, Akihiko Kudo
, Moritz F. Kuehnel
, Pramod Patil Kunturu
, Yi Hsuan Lai
, Chong Yong Lee
, Marcelino Maneiro
, Esther Edwardes Moore

Huu Chuong Nguyen, Aubrey R. Paris, Chanon Pornrungroj, Joost N.H. Reek, Erwin Reisner, Murielle Schreck, Wilson A. Smith, Han Sen Soo, Reiner Sebastian Sprick, Anirudh Venugopal, Qian Wang, Dominik Wielend, Martijn A. Zwijnenburg

Pure And Applied Chemistry

Research output: Contribution to journal › Comment/debate › peer-review

3 Citations (Scopus)

Abstract

Wilson Smith opened discussion of the paper by Michael Gratzel for the CU-AU electrodes, the proposed mechanism is that CO2 is converted to CO on the AU site, then diffuses on the surface to a Cu site where it hydrogenates to form higher order produces. Given that the system is highly porous and the local pH may be higher than the bulk solution, can you comment on the likelihood for the proposed mechanism (surface diffusion of CO), or if CO is formed in the gas phase, then re-adsorbs on the Cu surface from the solution? The two pathways have large implications on mechanistic understandings, and different approaches would be needed to optimise these steps in different ways.

Original language	English
Pages (from-to)	345-363
Number of pages	19
Journal	Faraday Discussions
Volume	215
Early online date	24 Jun 2019
DOIs	https://doi.org/10.1039/C9FD90023C
Publication status	Published - 1 Jul 2019

Keywords

CO2
CO absorption
photosynthesis

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10.1039/C9FD90023C

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Abe, R., Aitchison, C. M., Andrei, V., Beller, M., Cheung, D., Creissen, C. E., De La Peña O'Shea, V. A., Durrant, J. R., Grätzel, M., Hammarström, L., Haussener, S., In, S. I., Kalamaras, E., Kudo, A., Kuehnel, M. F., Kunturu, P. P., Lai, Y. H., Lee, C. Y., Maneiro, M., ... Zwijnenburg, M. A. (2019). Demonstrator devices for artificial photosynthesis: general discussion. Faraday Discussions, 215, 345-363. https://doi.org/10.1039/C9FD90023C

@article{3d3d63271d68450aa7588b042d973eff,

title = "Demonstrator devices for artificial photosynthesis: general discussion",

abstract = "Wilson Smith opened discussion of the paper by Michael Gratzel for the CU-AU electrodes, the proposed mechanism is that CO2 is converted to CO on the AU site, then diffuses on the surface to a Cu site where it hydrogenates to form higher order produces. Given that the system is highly porous and the local pH may be higher than the bulk solution, can you comment on the likelihood for the proposed mechanism (surface diffusion of CO), or if CO is formed in the gas phase, then re-adsorbs on the Cu surface from the solution? The two pathways have large implications on mechanistic understandings, and different approaches would be needed to optimise these steps in different ways.",

keywords = "CO2, CO absorption, photosynthesis",

author = "Ryu Abe and Aitchison, \{Catherine M.\} and Virgil Andrei and Matthias Beller and Daniel Cheung and Creissen, \{Charles E.\} and \{De La Pe{\~n}a O'Shea\}, \{V{\'i}ctor A.\} and Durrant, \{James R.\} and Michael Gr{\"a}tzel and Leif Hammarstr{\"o}m and Sophia Haussener and In, \{Su Il\} and Evangelos Kalamaras and Akihiko Kudo and Kuehnel, \{Moritz F.\} and Kunturu, \{Pramod Patil\} and Lai, \{Yi Hsuan\} and Lee, \{Chong Yong\} and Marcelino Maneiro and Moore, \{Esther Edwardes\} and Nguyen, \{Huu Chuong\} and Paris, \{Aubrey R.\} and Chanon Pornrungroj and Reek, \{Joost N.H.\} and Erwin Reisner and Murielle Schreck and Smith, \{Wilson A.\} and Soo, \{Han Sen\} and Sprick, \{Reiner Sebastian\} and Anirudh Venugopal and Qian Wang and Dominik Wielend and Zwijnenburg, \{Martijn A.\}",

year = "2019",

month = jul,

day = "1",

doi = "10.1039/C9FD90023C",

language = "English",

volume = "215",

pages = "345--363",

journal = "Faraday Discussions",

issn = "1359-6640",

publisher = "Royal Society of Chemistry",

}

Abe, R, Aitchison, CM, Andrei, V, Beller, M, Cheung, D, Creissen, CE, De La Peña O'Shea, VA, Durrant, JR, Grätzel, M, Hammarström, L, Haussener, S, In, SI, Kalamaras, E, Kudo, A, Kuehnel, MF, Kunturu, PP, Lai, YH, Lee, CY, Maneiro, M, Moore, EE, Nguyen, HC, Paris, AR, Pornrungroj, C, Reek, JNH, Reisner, E, Schreck, M, Smith, WA, Soo, HS, Sprick, RS, Venugopal, A, Wang, Q, Wielend, D & Zwijnenburg, MA 2019, 'Demonstrator devices for artificial photosynthesis: general discussion', Faraday Discussions, vol. 215, pp. 345-363. https://doi.org/10.1039/C9FD90023C

TY - JOUR

T1 - Demonstrator devices for artificial photosynthesis

T2 - general discussion

AU - Abe, Ryu

AU - Aitchison, Catherine M.

AU - Andrei, Virgil

AU - Beller, Matthias

AU - Cheung, Daniel

AU - Creissen, Charles E.

AU - De La Peña O'Shea, Víctor A.

AU - Durrant, James R.

AU - Grätzel, Michael

AU - Hammarström, Leif

AU - Haussener, Sophia

AU - In, Su Il

AU - Kalamaras, Evangelos

AU - Kudo, Akihiko

AU - Kuehnel, Moritz F.

AU - Kunturu, Pramod Patil

AU - Lai, Yi Hsuan

AU - Lee, Chong Yong

AU - Maneiro, Marcelino

AU - Moore, Esther Edwardes

AU - Nguyen, Huu Chuong

AU - Paris, Aubrey R.

AU - Pornrungroj, Chanon

AU - Reek, Joost N.H.

AU - Reisner, Erwin

AU - Schreck, Murielle

AU - Smith, Wilson A.

AU - Soo, Han Sen

AU - Sprick, Reiner Sebastian

AU - Venugopal, Anirudh

AU - Wang, Qian

AU - Wielend, Dominik

AU - Zwijnenburg, Martijn A.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Wilson Smith opened discussion of the paper by Michael Gratzel for the CU-AU electrodes, the proposed mechanism is that CO2 is converted to CO on the AU site, then diffuses on the surface to a Cu site where it hydrogenates to form higher order produces. Given that the system is highly porous and the local pH may be higher than the bulk solution, can you comment on the likelihood for the proposed mechanism (surface diffusion of CO), or if CO is formed in the gas phase, then re-adsorbs on the Cu surface from the solution? The two pathways have large implications on mechanistic understandings, and different approaches would be needed to optimise these steps in different ways.

AB - Wilson Smith opened discussion of the paper by Michael Gratzel for the CU-AU electrodes, the proposed mechanism is that CO2 is converted to CO on the AU site, then diffuses on the surface to a Cu site where it hydrogenates to form higher order produces. Given that the system is highly porous and the local pH may be higher than the bulk solution, can you comment on the likelihood for the proposed mechanism (surface diffusion of CO), or if CO is formed in the gas phase, then re-adsorbs on the Cu surface from the solution? The two pathways have large implications on mechanistic understandings, and different approaches would be needed to optimise these steps in different ways.

KW - CO2

KW - CO absorption

KW - photosynthesis

UR - https://www.scopus.com/pages/publications/85068516887

U2 - 10.1039/C9FD90023C

DO - 10.1039/C9FD90023C

M3 - Comment/debate

C2 - 31231738

AN - SCOPUS:85068516887

SN - 1359-6640

VL - 215

SP - 345

EP - 363

JO - Faraday Discussions

JF - Faraday Discussions

ER -

Demonstrator devices for artificial photosynthesis: general discussion

Abstract

Keywords

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