Abstract
A general thermolysis reaction for the transformation of Group 1 TMP compounds (LiTMP, NaTMP, KTMP) to 1-aza-allylic TTHP derivatives is reported. TMEDA accelerates the reaction and produces the crystalline complexes [(TMEDA)LiTTHP] and [(TMEDA·NaTTHP)2]. Methane elimination during the transformational process was confirmed via TVA coupled to MS.
| Language | English |
|---|---|
| Pages | 10588-10591 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 50 |
| Issue number | 73 |
| Early online date | 24 Jul 2014 |
| DOIs | |
| Publication status | Published - 21 Sep 2014 |
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Keywords
- dehydromethylation
- alkali metal salts
- utility amide
- 2,2,6,6-tetramethylpiperidide
- general thermolysis reaction
- LiTMP
- NaTMP
- KTMP
- group 1 TMP compounds
- crystalline complexes
- methane elimination
- lithium TMP
Cite this
}
Dehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP). / Kennedy, Alan R.; Leenhouts, Sarah M.; Liggat, John J.; Martínez-Martínez, Antonio J.; Miller, Kimberley; Mulvey, Robert E.; O'Hara, Charles T.; O'Keefe, Philip; Steven, Alan.
In: Chemical Communications, Vol. 50, No. 73, 21.09.2014, p. 10588-10591.Research output: Contribution to journal › Article
TY - JOUR
T1 - Dehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP)
AU - Kennedy, Alan R.
AU - Leenhouts, Sarah M.
AU - Liggat, John J.
AU - Martínez-Martínez, Antonio J.
AU - Miller, Kimberley
AU - Mulvey, Robert E.
AU - O'Hara, Charles T.
AU - O'Keefe, Philip
AU - Steven, Alan
PY - 2014/9/21
Y1 - 2014/9/21
N2 - A general thermolysis reaction for the transformation of Group 1 TMP compounds (LiTMP, NaTMP, KTMP) to 1-aza-allylic TTHP derivatives is reported. TMEDA accelerates the reaction and produces the crystalline complexes [(TMEDA)LiTTHP] and [(TMEDA·NaTTHP)2]. Methane elimination during the transformational process was confirmed via TVA coupled to MS.
AB - A general thermolysis reaction for the transformation of Group 1 TMP compounds (LiTMP, NaTMP, KTMP) to 1-aza-allylic TTHP derivatives is reported. TMEDA accelerates the reaction and produces the crystalline complexes [(TMEDA)LiTTHP] and [(TMEDA·NaTTHP)2]. Methane elimination during the transformational process was confirmed via TVA coupled to MS.
KW - dehydromethylation
KW - alkali metal salts
KW - utility amide
KW - 2,2,6,6-tetramethylpiperidide
KW - general thermolysis reaction
KW - LiTMP
KW - NaTMP
KW - KTMP
KW - group 1 TMP compounds
KW - crystalline complexes
KW - methane elimination
KW - lithium TMP
UR - http://www.scopus.com/inward/record.url?scp=84906228476&partnerID=8YFLogxK
U2 - 10.1039/c4cc04959d
DO - 10.1039/c4cc04959d
M3 - Article
VL - 50
SP - 10588
EP - 10591
JO - Chemical Communications
T2 - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 73
ER -