Projects per year
Abstract
A general thermolysis reaction for the transformation of Group 1 TMP compounds (LiTMP, NaTMP, KTMP) to 1-aza-allylic TTHP derivatives is reported. TMEDA accelerates the reaction and produces the crystalline complexes [(TMEDA)LiTTHP] and [(TMEDA·NaTTHP)2]. Methane elimination during the transformational process was confirmed via TVA coupled to MS.
Original language | English |
---|---|
Pages (from-to) | 10588-10591 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 50 |
Issue number | 73 |
Early online date | 24 Jul 2014 |
DOIs | |
Publication status | Published - 21 Sep 2014 |
Keywords
- dehydromethylation
- alkali metal salts
- utility amide
- 2,2,6,6-tetramethylpiperidide
- general thermolysis reaction
- LiTMP
- NaTMP
- KTMP
- group 1 TMP compounds
- crystalline complexes
- methane elimination
- lithium TMP
Fingerprint
Dive into the research topics of 'Dehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP)'. Together they form a unique fingerprint.Projects
- 3 Finished
-
A co-operative bimetallic approach for the transformation of lithiation
EPSRC (Engineering and Physical Sciences Research Council)
1/03/13 → 29/02/16
Project: Research
-
Chiral Concepts in s-Block Metal Amide Chemistry
EPSRC (Engineering and Physical Sciences Research Council)
1/10/11 → 30/09/16
Project: Research Fellowship