Crystal structures of the solvates trans-[RhCl2(MeOH){C6H3-2,6-(CH2PCy2)2}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH){C6H3-2,6-(CH2PCy2)2}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3

R J  CROSS; A R  KENNEDY; L  MANOJLOVICMUIR; K W  MUIR

doi:10.1016/0022-328X(94)05361-E

Crystal structures of the solvates trans-[RhCl2(MeOH){C6H3-2,6-(CH2PCy2)2}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH){C6H3-2,6-(CH2PCy2)2}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3

R J CROSS, A R KENNEDY, L MANOJLOVICMUIR, K W MUIR

Pure And Applied Chemistry

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Abstract

The terdentate ligands C6H3-2,6-(CH(2)PCy(2))(2) (PCP: Cy = cyclohexyl) in the octahedral solvento complexes trans-[RhCl2(MeOH)(PCP)] and trans-[RhCl2(EtOH)(PCP)] adopt conformations which minimise the interactions between the sterically demanding Cy groups and the trans chlorides. Comparison of these structures with those of related molecules, including square-pyramidal and square-planar species, suggests an explanation for the different structural types obtained as products from reactions of RhCl3.3H(2)O and various ligands C6H4-1,3-(CH(2)ER(2))(2) with E = N or P.

Original language	English
Pages (from-to)	243-249
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	493
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(94)05361-E
Publication status	Published - 17 May 1995

Keywords

rhodium
terdentate ligands
crystal structures
orthometallation
metal-carbon bonds
ligands
oxidative-addition
iridium

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10.1016/0022-328X(94)05361-E

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CROSS, R. J., KENNEDY, A. R., MANOJLOVICMUIR, L., & MUIR, K. W. (1995). Crystal structures of the solvates trans-[RhCl2(MeOH){C6H3-2,6-(CH2PCy2)2}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH){C6H3-2,6-(CH2PCy2)2}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3. Journal of Organometallic Chemistry, 493(1-2), 243-249. https://doi.org/10.1016/0022-328X(94)05361-E

@article{94e32933d50e4b05912962719c8571e4,

title = "Crystal structures of the solvates trans-[RhCl2(MeOH)\{C6H3-2,6-(CH2PCy2)2\}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH)\{C6H3-2,6-(CH2PCy2)2\}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3",

abstract = "The terdentate ligands C6H3-2,6-(CH(2)PCy(2))(2) (PCP: Cy = cyclohexyl) in the octahedral solvento complexes trans-[RhCl2(MeOH)(PCP)] and trans-[RhCl2(EtOH)(PCP)] adopt conformations which minimise the interactions between the sterically demanding Cy groups and the trans chlorides. Comparison of these structures with those of related molecules, including square-pyramidal and square-planar species, suggests an explanation for the different structural types obtained as products from reactions of RhCl3.3H(2)O and various ligands C6H4-1,3-(CH(2)ER(2))(2) with E = N or P.",

keywords = "rhodium, terdentate ligands, crystal structures, orthometallation, metal-carbon bonds, ligands, oxidative-addition, iridium",

author = "CROSS, \{R J\} and KENNEDY, \{A R\} and L MANOJLOVICMUIR and MUIR, \{K W\}",

year = "1995",

month = may,

day = "17",

doi = "10.1016/0022-328X(94)05361-E",

language = "English",

volume = "493",

pages = "243--249",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

}

CROSS, RJ, KENNEDY, AR, MANOJLOVICMUIR, L & MUIR, KW 1995, 'Crystal structures of the solvates trans-[RhCl2(MeOH){C6H3-2,6-(CH2PCy2)2}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH){C6H3-2,6-(CH2PCy2)2}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3', Journal of Organometallic Chemistry, vol. 493, no. 1-2, pp. 243-249. https://doi.org/10.1016/0022-328X(94)05361-E

Crystal structures of the solvates trans-[RhCl2(MeOH){C6H3-2,6-(CH2PCy2)2}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH){C6H3-2,6-(CH2PCy2)2}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3. / CROSS, R J ; KENNEDY, A R ; MANOJLOVICMUIR, L et al.
In: Journal of Organometallic Chemistry, Vol. 493, No. 1-2, 17.05.1995, p. 243-249.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal structures of the solvates trans-[RhCl2(MeOH){C6H3-2,6-(CH2PCy2)2}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH){C6H3-2,6-(CH2PCy2)2}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3

AU - CROSS, R J

AU - KENNEDY, A R

AU - MANOJLOVICMUIR, L

AU - MUIR, K W

PY - 1995/5/17

Y1 - 1995/5/17

N2 - The terdentate ligands C6H3-2,6-(CH(2)PCy(2))(2) (PCP: Cy = cyclohexyl) in the octahedral solvento complexes trans-[RhCl2(MeOH)(PCP)] and trans-[RhCl2(EtOH)(PCP)] adopt conformations which minimise the interactions between the sterically demanding Cy groups and the trans chlorides. Comparison of these structures with those of related molecules, including square-pyramidal and square-planar species, suggests an explanation for the different structural types obtained as products from reactions of RhCl3.3H(2)O and various ligands C6H4-1,3-(CH(2)ER(2))(2) with E = N or P.

AB - The terdentate ligands C6H3-2,6-(CH(2)PCy(2))(2) (PCP: Cy = cyclohexyl) in the octahedral solvento complexes trans-[RhCl2(MeOH)(PCP)] and trans-[RhCl2(EtOH)(PCP)] adopt conformations which minimise the interactions between the sterically demanding Cy groups and the trans chlorides. Comparison of these structures with those of related molecules, including square-pyramidal and square-planar species, suggests an explanation for the different structural types obtained as products from reactions of RhCl3.3H(2)O and various ligands C6H4-1,3-(CH(2)ER(2))(2) with E = N or P.

KW - rhodium

KW - terdentate ligands

KW - crystal structures

KW - orthometallation

KW - metal-carbon bonds

KW - ligands

KW - oxidative-addition

KW - iridium

U2 - 10.1016/0022-328X(94)05361-E

DO - 10.1016/0022-328X(94)05361-E

M3 - Article

SN - 0022-328X

VL - 493

SP - 243

EP - 249

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Crystal structures of the solvates trans-[RhCl2(MeOH){C6H3-2,6-(CH2PCy2)2}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH){C6H3-2,6-(CH2PCy2)2}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3

Abstract

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