Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms

D  BARR; W  CLEGG; Robert Mulvey; R  SNAITH

doi:10.1039/C39840000079

Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms

D BARR, W CLEGG, Robert Mulvey, R SNAITH

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

110 Citations (Scopus)

Abstract

X-Ray crystallographic studies of the title compounds (Ph2CNLi·NC5H5)4, (1), and [CILi·OP(NMe2)3]4, (2) show them to have pseudo cubane tetrameric structures in which triply-bonding methyleneamino -nitrogen atoms [(1)] or chlorine atoms [(2)] hold together the tetrahedral Li4 frameworks.

Original language	English
Pages (from-to)	79-80
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39840000079
Publication status	Published - 1984

Keywords

crystal structures
chlorine atoms
nitrogen atoms

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10.1039/C39840000079

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title = "Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms",

abstract = "X-Ray crystallographic studies of the title compounds (Ph2CNLi·NC5H5)4, (1), and [CILi·OP(NMe2)3]4, (2) show them to have pseudo cubane tetrameric structures in which triply-bonding methyleneamino -nitrogen atoms [(1)] or chlorine atoms [(2)] hold together the tetrahedral Li4 frameworks.",

keywords = "crystal structures, chlorine atoms, nitrogen atoms",

author = "D BARR and W CLEGG and Robert Mulvey and R SNAITH",

year = "1984",

doi = "10.1039/C39840000079",

language = "English",

pages = "79--80",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

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Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms. / BARR, D ; CLEGG, W ; Mulvey, Robert et al.
In: Journal of the Chemical Society, Chemical Communications, No. 2, 1984, p. 79-80.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms

AU - BARR, D

AU - CLEGG, W

AU - Mulvey, Robert

AU - SNAITH, R

PY - 1984

Y1 - 1984

N2 - X-Ray crystallographic studies of the title compounds (Ph2CNLi·NC5H5)4, (1), and [CILi·OP(NMe2)3]4, (2) show them to have pseudo cubane tetrameric structures in which triply-bonding methyleneamino -nitrogen atoms [(1)] or chlorine atoms [(2)] hold together the tetrahedral Li4 frameworks.

AB - X-Ray crystallographic studies of the title compounds (Ph2CNLi·NC5H5)4, (1), and [CILi·OP(NMe2)3]4, (2) show them to have pseudo cubane tetrameric structures in which triply-bonding methyleneamino -nitrogen atoms [(1)] or chlorine atoms [(2)] hold together the tetrahedral Li4 frameworks.

KW - crystal structures

KW - chlorine atoms

KW - nitrogen atoms

U2 - 10.1039/C39840000079

DO - 10.1039/C39840000079

M3 - Article

SN - 0022-4936

SP - 79

EP - 80

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 2

ER -

Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms

Abstract

Keywords

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