Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms

D BARR, W CLEGG, Robert Mulvey, R SNAITH

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Abstract

X-Ray crystallographic studies of the title compounds (Ph2CNLi·NC5H5)4, (1), and [CILi·OP(NMe2)3]4, (2) show them to have pseudo cubane tetrameric structures in which triply-bonding methyleneamino -nitrogen atoms [(1)] or chlorine atoms [(2)] hold together the tetrahedral Li4 frameworks.
LanguageEnglish
Pages79-80
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number2
DOIs
Publication statusPublished - 1984

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Chlorine
Nitrogen
X-Rays

Keywords

  • crystal structures
  • chlorine atoms
  • nitrogen atoms

Cite this

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title = "Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms",
abstract = "X-Ray crystallographic studies of the title compounds (Ph2CNLi·NC5H5)4, (1), and [CILi·OP(NMe2)3]4, (2) show them to have pseudo cubane tetrameric structures in which triply-bonding methyleneamino -nitrogen atoms [(1)] or chlorine atoms [(2)] hold together the tetrahedral Li4 frameworks.",
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T1 - Crystal structures of (Ph2CNLi·NC5H5)4 and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3 triangles by nitrogen and by chlorine atoms

AU - BARR, D

AU - CLEGG, W

AU - Mulvey, Robert

AU - SNAITH, R

PY - 1984

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N2 - X-Ray crystallographic studies of the title compounds (Ph2CNLi·NC5H5)4, (1), and [CILi·OP(NMe2)3]4, (2) show them to have pseudo cubane tetrameric structures in which triply-bonding methyleneamino -nitrogen atoms [(1)] or chlorine atoms [(2)] hold together the tetrahedral Li4 frameworks.

AB - X-Ray crystallographic studies of the title compounds (Ph2CNLi·NC5H5)4, (1), and [CILi·OP(NMe2)3]4, (2) show them to have pseudo cubane tetrameric structures in which triply-bonding methyleneamino -nitrogen atoms [(1)] or chlorine atoms [(2)] hold together the tetrahedral Li4 frameworks.

KW - crystal structures

KW - chlorine atoms

KW - nitrogen atoms

U2 - 10.1039/C39840000079

DO - 10.1039/C39840000079

M3 - Article

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JO - Journal of the Chemical Society, Chemical Communications

T2 - Journal of the Chemical Society, Chemical Communications

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