Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides

S M Aucott, H L Milton, S D Robertson, A M Z Slawin, J D Woollins

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The X-ray structures of dibenzo[ce]-1,2dithiine, dibenzo[ce]-1,2-dithiine-5,5-dioxide, dibenzo[ce]-1,2-dithiine-5,5,6-trioxide, and dibenzo[ce]-1, 2-dithiine-5,5,6,6-tetraoxide are reported and compared with the related "constrained" naphthalene derivatives. The S-S distances vary upon oxidation of the S centers in the order S-S < SO-S > SO2-S < SO2-SO > SO2-SO2 i.e. the most oxidized sulfur atoms do not lead to the longest bond lengths.

Original languageEnglish
Pages (from-to)346-351
Number of pages6
JournalHeteroatom Chemistry
Volume16
Issue number5
DOIs
Publication statusPublished - 2005

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Bond length
Sulfur
Oxides
Crystal structure
Derivatives
X rays
Atoms
Oxidation
naphthalene

Keywords

  • naphthalene derivatives
  • crystal structures

Cite this

Aucott, S. M., Milton, H. L., Robertson, S. D., Slawin, A. M. Z., & Woollins, J. D. (2005). Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides. Heteroatom Chemistry, 16(5), 346-351. https://doi.org/10.1002/hc.20101
Aucott, S M ; Milton, H L ; Robertson, S D ; Slawin, A M Z ; Woollins, J D . / Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides. In: Heteroatom Chemistry. 2005 ; Vol. 16, No. 5. pp. 346-351.
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Aucott, SM, Milton, HL, Robertson, SD, Slawin, AMZ & Woollins, JD 2005, 'Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides', Heteroatom Chemistry, vol. 16, no. 5, pp. 346-351. https://doi.org/10.1002/hc.20101

Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides. / Aucott, S M ; Milton, H L ; Robertson, S D ; Slawin, A M Z ; Woollins, J D .

In: Heteroatom Chemistry, Vol. 16, No. 5, 2005, p. 346-351.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides

AU - Aucott, S M

AU - Milton, H L

AU - Robertson, S D

AU - Slawin, A M Z

AU - Woollins, J D

PY - 2005

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AB - The X-ray structures of dibenzo[ce]-1,2dithiine, dibenzo[ce]-1,2-dithiine-5,5-dioxide, dibenzo[ce]-1,2-dithiine-5,5,6-trioxide, and dibenzo[ce]-1, 2-dithiine-5,5,6,6-tetraoxide are reported and compared with the related "constrained" naphthalene derivatives. The S-S distances vary upon oxidation of the S centers in the order S-S < SO-S > SO2-S < SO2-SO > SO2-SO2 i.e. the most oxidized sulfur atoms do not lead to the longest bond lengths.

KW - naphthalene derivatives

KW - crystal structures

U2 - 10.1002/hc.20101

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JO - Heteroatom Chemistry

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