Crystal structure of sodium iodide·(diglyme): An unprecedented bridging role for diglyme

Robert Mulvey, W. Clegg, Donald Barr, R. Snaith

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The diglyme adduct of sodium iodide, NaI·(CH3OCH2CH2)2O, has been structurally characterized by X-ray diffraction. It forms infinite zig-zag chains which, unlike most complexes of the salt, retain NaI bonds. In addition, diglyme molecules bridge pairs of Na atoms through four-co-ordinate O atoms, so representing a new role for this neutral oxygen donor.
LanguageEnglish
Pages2109-2111
Number of pages3
JournalPolyhedron
Volume5
Issue number12
DOIs
Publication statusPublished - 1986

Fingerprint

Sodium Iodide
sodium iodides
Crystal structure
Sodium
Atoms
crystal structure
adducts
atoms
Salts
Oxygen
salts
X ray diffraction
Molecules
oxygen
diffraction
molecules
x rays
diglyme

Keywords

  • crystal structure
  • sodium iodide

Cite this

Mulvey, Robert ; Clegg, W. ; Barr, Donald ; Snaith, R. . / Crystal structure of sodium iodide·(diglyme) : An unprecedented bridging role for diglyme. In: Polyhedron. 1986 ; Vol. 5, No. 12. pp. 2109-2111.
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Crystal structure of sodium iodide·(diglyme) : An unprecedented bridging role for diglyme. / Mulvey, Robert; Clegg, W.; Barr, Donald; Snaith, R. .

In: Polyhedron, Vol. 5, No. 12, 1986, p. 2109-2111.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Crystal structure of sodium iodide·(diglyme)

T2 - Polyhedron

AU - Mulvey, Robert

AU - Clegg, W.

AU - Barr, Donald

AU - Snaith, R.

PY - 1986

Y1 - 1986

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AB - The diglyme adduct of sodium iodide, NaI·(CH3OCH2CH2)2O, has been structurally characterized by X-ray diffraction. It forms infinite zig-zag chains which, unlike most complexes of the salt, retain NaI bonds. In addition, diglyme molecules bridge pairs of Na atoms through four-co-ordinate O atoms, so representing a new role for this neutral oxygen donor.

KW - crystal structure

KW - sodium iodide

U2 - 10.1016/S0277-5387(00)87147-8

DO - 10.1016/S0277-5387(00)87147-8

M3 - Article

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EP - 2111

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

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