Crystal structure of 3-chloro-N-(2-nitrophenyl)benzamide

R. Moreno-Fuquen; A. Azcarate; A. R. Kennedy

doi:10.1107/S2056989015014620

Crystal structure of 3-chloro-N-(2-nitrophenyl)benzamide

R. Moreno-Fuquen, A. Azcarate, A. R. Kennedy

Pure And Applied Chemistry

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Abstract

In the title compound, C13H9ClN2O3, the mean plane of the central amide fragment (r.m.s. deviation = 0.016 Å) subtends dihedral angles of 15.2 (2) and 8.2 (2)° with the chloro- and nitro-substituted benzene rings, respectively. An intramolecular N-H...O hydrogen bond generates an S(6) ring. In the crystal, molecules are linked by weak C-H...O hydrogen bonds, forming C(7) chains which propagate along [010], but no Cl...Cl short contacts are observed.

Original language	English
Article number	o674
Number of pages	8
Journal	Acta Crystallographica Section E: Structure Reports
Volume	71
Issue number	9
DOIs	https://doi.org/10.1107/S2056989015014620
Publication status	Published - Sept 2015

Keywords

benzene rings
hydrogen bond
crystals

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10.1107/S2056989015014620

Moreno-Fuquen-etal-ACECC-2015-Crystal-structure-of-3-chloro-N-(2-nitrophenyl)-benzamideFinal published version, 318 KBLicence: CC BY 4.0

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Kennedy, A.
Pure And Applied Chemistry
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title = "Crystal structure of 3-chloro-N-(2-nitrophenyl)benzamide",

abstract = "In the title compound, C13H9ClN2O3, the mean plane of the central amide fragment (r.m.s. deviation = 0.016 {\AA}) subtends dihedral angles of 15.2 (2) and 8.2 (2)° with the chloro- and nitro-substituted benzene rings, respectively. An intramolecular N-H...O hydrogen bond generates an S(6) ring. In the crystal, molecules are linked by weak C-H...O hydrogen bonds, forming C(7) chains which propagate along [010], but no Cl...Cl short contacts are observed.",

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year = "2015",

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language = "English",

volume = "71",

journal = "Acta Crystallographica Section E: Structure Reports",

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T1 - Crystal structure of 3-chloro-N-(2-nitrophenyl)benzamide

AU - Moreno-Fuquen, R.

AU - Azcarate, A.

AU - Kennedy, A. R.

PY - 2015/9

Y1 - 2015/9

N2 - In the title compound, C13H9ClN2O3, the mean plane of the central amide fragment (r.m.s. deviation = 0.016 Å) subtends dihedral angles of 15.2 (2) and 8.2 (2)° with the chloro- and nitro-substituted benzene rings, respectively. An intramolecular N-H...O hydrogen bond generates an S(6) ring. In the crystal, molecules are linked by weak C-H...O hydrogen bonds, forming C(7) chains which propagate along [010], but no Cl...Cl short contacts are observed.

AB - In the title compound, C13H9ClN2O3, the mean plane of the central amide fragment (r.m.s. deviation = 0.016 Å) subtends dihedral angles of 15.2 (2) and 8.2 (2)° with the chloro- and nitro-substituted benzene rings, respectively. An intramolecular N-H...O hydrogen bond generates an S(6) ring. In the crystal, molecules are linked by weak C-H...O hydrogen bonds, forming C(7) chains which propagate along [010], but no Cl...Cl short contacts are observed.

KW - benzene rings

KW - hydrogen bond

KW - crystals

U2 - 10.1107/S2056989015014620

DO - 10.1107/S2056989015014620

M3 - Article

SN - 1600-5368

VL - 71

JO - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

IS - 9

M1 - o674

ER -

Crystal structure of 3-chloro-N-(2-nitrophenyl)benzamide

Abstract

Keywords

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