Crystal structure of 3-chloro-N-(2-nitrophenyl)benzamide

R. Moreno-Fuquen, A. Azcarate, A. R. Kennedy

Research output: Contribution to journalArticle

Abstract

In the title compound, C13H9ClN2O3, the mean plane of the central amide fragment (r.m.s. deviation = 0.016 Å) subtends dihedral angles of 15.2 (2) and 8.2 (2)° with the chloro- and nitro-substituted benzene rings, respectively. An intra­molecular N-H...O hydrogen bond generates an S(6) ring. In the crystal, mol­ecules are linked by weak C-H...O hydrogen bonds, forming C(7) chains which propagate along [010], but no Cl...Cl short contacts are observed.
LanguageEnglish
Article numbero674
Number of pages8
JournalActa Crystallographica Section E: Structure Reports
Volume71
Issue number9
DOIs
Publication statusPublished - Sep 2015

Fingerprint

Hydrogen bonds
Crystal structure
hydrogen bonds
crystal structure
Nitrobenzene
rings
Dihedral angle
Amides
amides
dihedral angle
benzene
fragments
deviation
Crystals
crystals
benzamide

Keywords

  • benzene rings
  • hydrogen bond
  • crystals

Cite this

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title = "Crystal structure of 3-chloro-N-(2-nitrophenyl)benzamide",
abstract = "In the title compound, C13H9ClN2O3, the mean plane of the central amide fragment (r.m.s. deviation = 0.016 {\AA}) subtends dihedral angles of 15.2 (2) and 8.2 (2)° with the chloro- and nitro-substituted benzene rings, respectively. An intra­molecular N-H...O hydrogen bond generates an S(6) ring. In the crystal, mol­ecules are linked by weak C-H...O hydrogen bonds, forming C(7) chains which propagate along [010], but no Cl...Cl short contacts are observed.",
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journal = "Acta Crystallographica Section E: Structure Reports",
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Crystal structure of 3-chloro-N-(2-nitrophenyl)benzamide. / Moreno-Fuquen, R.; Azcarate, A.; Kennedy, A. R.

In: Acta Crystallographica Section E: Structure Reports, Vol. 71, No. 9, o674, 09.2015.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Crystal structure of 3-chloro-N-(2-nitrophenyl)benzamide

AU - Moreno-Fuquen, R.

AU - Azcarate, A.

AU - Kennedy, A. R.

PY - 2015/9

Y1 - 2015/9

N2 - In the title compound, C13H9ClN2O3, the mean plane of the central amide fragment (r.m.s. deviation = 0.016 Å) subtends dihedral angles of 15.2 (2) and 8.2 (2)° with the chloro- and nitro-substituted benzene rings, respectively. An intra­molecular N-H...O hydrogen bond generates an S(6) ring. In the crystal, mol­ecules are linked by weak C-H...O hydrogen bonds, forming C(7) chains which propagate along [010], but no Cl...Cl short contacts are observed.

AB - In the title compound, C13H9ClN2O3, the mean plane of the central amide fragment (r.m.s. deviation = 0.016 Å) subtends dihedral angles of 15.2 (2) and 8.2 (2)° with the chloro- and nitro-substituted benzene rings, respectively. An intra­molecular N-H...O hydrogen bond generates an S(6) ring. In the crystal, mol­ecules are linked by weak C-H...O hydrogen bonds, forming C(7) chains which propagate along [010], but no Cl...Cl short contacts are observed.

KW - benzene rings

KW - hydrogen bond

KW - crystals

U2 - 10.1107/S2056989015014620

DO - 10.1107/S2056989015014620

M3 - Article

VL - 71

JO - Acta Crystallographica Section E: Structure Reports

T2 - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

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