Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n

D. Barr; W.  Clegg; Robert Mulvey; D.  Reed; R. Snaith

doi:10.1002/anie.198503281

Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n

D. Barr, W. Clegg, Robert Mulvey, D. Reed, R. Snaith

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The first dimeric lithium alkylideneamide with a μ2-nitrogen ligand and resulting Li2N2 ring is the solvent-stabilized title compound 1. The ring is exactly planar. Both the dimer 1 and the monomer are present in aromatic solvents, as was confirmed by cryoscopic Mr determinations in combination with high-field 1H- and 7Li-NMR measurements

Original language	English
Pages (from-to)	328-329
Number of pages	2
Journal	Angewandte Chemie International Edition
Volume	24
Issue number	4
DOIs	https://doi.org/10.1002/anie.198503281
Publication status	Published - Apr 1985

Keywords

crystal solutions
crystal structure
aromatic solvents

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10.1002/anie.198503281

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title = "Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n",

abstract = "The first dimeric lithium alkylideneamide with a μ2-nitrogen ligand and resulting Li2N2 ring is the solvent-stabilized title compound 1. The ring is exactly planar. Both the dimer 1 and the monomer are present in aromatic solvents, as was confirmed by cryoscopic Mr determinations in combination with high-field 1H- and 7Li-NMR measurements",

keywords = "crystal solutions, crystal structure, aromatic solvents",

author = "D. Barr and W. Clegg and Robert Mulvey and D. Reed and R. Snaith",

year = "1985",

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doi = "10.1002/anie.198503281",

language = "English",

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journal = "Angewandte Chemie International Edition",

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T1 - Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n

AU - Barr, D.

AU - Clegg, W.

AU - Mulvey, Robert

AU - Reed, D.

AU - Snaith, R.

PY - 1985/4

Y1 - 1985/4

N2 - The first dimeric lithium alkylideneamide with a μ2-nitrogen ligand and resulting Li2N2 ring is the solvent-stabilized title compound 1. The ring is exactly planar. Both the dimer 1 and the monomer are present in aromatic solvents, as was confirmed by cryoscopic Mr determinations in combination with high-field 1H- and 7Li-NMR measurements

AB - The first dimeric lithium alkylideneamide with a μ2-nitrogen ligand and resulting Li2N2 ring is the solvent-stabilized title compound 1. The ring is exactly planar. Both the dimer 1 and the monomer are present in aromatic solvents, as was confirmed by cryoscopic Mr determinations in combination with high-field 1H- and 7Li-NMR measurements

KW - crystal solutions

KW - crystal structure

KW - aromatic solvents

U2 - 10.1002/anie.198503281

DO - 10.1002/anie.198503281

M3 - Article

SN - 1433-7851

VL - 24

SP - 328

EP - 329

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 4

ER -

Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n

Abstract

Keywords

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