Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n

D. Barr, W. Clegg, Robert Mulvey, D. Reed, R. Snaith

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The first dimeric lithium alkylideneamide with a μ2-nitrogen ligand and resulting Li2N2 ring is the solvent-stabilized title compound 1. The ring is exactly planar. Both the dimer 1 and the monomer are present in aromatic solvents, as was confirmed by cryoscopic Mr determinations in combination with high-field 1H- and 7Li-NMR measurements
LanguageEnglish
Pages328-329
Number of pages2
JournalAngewandte Chemie International Edition
Volume24
Issue number4
DOIs
Publication statusPublished - Apr 1985

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Lithium
Nitrogen
Ligands
Proton Magnetic Resonance Spectroscopy

Keywords

  • crystal solutions
  • crystal structure
  • aromatic solvents

Cite this

Barr, D. ; Clegg, W. ; Mulvey, Robert ; Reed, D. ; Snaith, R. / Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n. In: Angewandte Chemie International Edition. 1985 ; Vol. 24, No. 4. pp. 328-329.
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Crystal and Solution Structures of [tBu2CNLi·OP(NMe2)3]n. / Barr, D.; Clegg, W. ; Mulvey, Robert; Reed, D. ; Snaith, R.

In: Angewandte Chemie International Edition, Vol. 24, No. 4, 04.1985, p. 328-329.

Research output: Contribution to journalArticle

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AB - The first dimeric lithium alkylideneamide with a μ2-nitrogen ligand and resulting Li2N2 ring is the solvent-stabilized title compound 1. The ring is exactly planar. Both the dimer 1 and the monomer are present in aromatic solvents, as was confirmed by cryoscopic Mr determinations in combination with high-field 1H- and 7Li-NMR measurements

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KW - aromatic solvents

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