Crossing organolithium compounds with organolithium compounds: molecular squares and a cage-encapsulating reaction

Andrew A. Fyfe, Alan R. Kennedy, Jan Klett, Robert E. Mulvey

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Triple-crossed: An extraordinary crossing reaction involving three popular utility organolithium reagents nBuLi, LiTMP (TMP=2,2,6,6-tetramethylpiperidide), and LiC5H5 leads to the unexpected deprotonation of C5H5− anions to C5H42− dianions, which was manifested through the trapping of the hexameric nBuLi cage by a [{Li(μ-TMP)Li(μ-C5H5)}4] molecular square ring (see picture).
LanguageEnglish
Pages7776-7780
Number of pages5
JournalAngewandte Chemie
Volume50
Issue number34
DOIs
Publication statusPublished - 16 Aug 2011

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Thymidine Monophosphate
Anions
2,2,6,6-tetramethylpiperidide

Keywords

  • cyclopentadienyl ligands
  • host-guest systems
  • lithium
  • metalation
  • X-ray diffraction
  • metal mediated manganation (ii)
  • solid-state structures
  • lithium compounds
  • alkali
  • reactivities
  • reagents
  • derivatives
  • superbases
  • complexes

Cite this

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abstract = "Triple-crossed: An extraordinary crossing reaction involving three popular utility organolithium reagents nBuLi, LiTMP (TMP=2,2,6,6-tetramethylpiperidide), and LiC5H5 leads to the unexpected deprotonation of C5H5− anions to C5H42− dianions, which was manifested through the trapping of the hexameric nBuLi cage by a [{Li(μ-TMP)Li(μ-C5H5)}4] molecular square ring (see picture).",
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Crossing organolithium compounds with organolithium compounds : molecular squares and a cage-encapsulating reaction. / Fyfe, Andrew A.; Kennedy, Alan R.; Klett, Jan; Mulvey, Robert E.

In: Angewandte Chemie, Vol. 50, No. 34, 16.08.2011, p. 7776-7780.

Research output: Contribution to journalArticle

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KW - alkali

KW - reactivities

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KW - derivatives

KW - superbases

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