Controlled stabilisation of silicic acid below pH 9 using poly(1-vinylimidazole)

Vadim V. Annenkov, Elena N. Danilovtseva, Yelena V. Likhoshway, Siddharth V. Patwardhan, Carole C. Perry

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

We show, for the first time, inhibition of silicic acid condensation over a wide range of pH, especially below 9 using certain molecular mass fractions of poly(1-vinylimidazole) (PVI). This is achieved by stabilisation of molybdate-active Si species, which are crucial to condensation and growth to form silica. The structure of the resulting composites depends on the molecular mass of the PVI chains. Long-chain macromolecules can ''encapsulate'' Si species giving rise to stable soluble complexes. Short PVI chains stimulate association of silica particles and at neutral pH precipitation occurs. Protonation of imidazole units in acidic pH results in dissolution of the precipitates. We believe that the results presented herein using PVI as a model system will help elucidate the mechanisms underpinning the molecular interactions between (bio) macromolecules and inorganic materials.

LanguageEnglish
Pages553-559
Number of pages7
JournalJournal of Materials Chemistry
Volume18
Issue number5
DOIs
Publication statusPublished - 2008

Fingerprint

Silicic Acid
Molecular mass
Macromolecules
Silicon Dioxide
Condensation
Stabilization
Silica
Molecular interactions
Acids
Protonation
Precipitates
Dissolution
Association reactions
Composite materials
poly(1-vinylimidazole)
molybdate
imidazole

Keywords

  • aqueous solution
  • silicification
  • viscosity
  • complexes
  • diatoms

Cite this

Annenkov, V. V., Danilovtseva, E. N., Likhoshway, Y. V., Patwardhan, S. V., & Perry, C. C. (2008). Controlled stabilisation of silicic acid below pH 9 using poly(1-vinylimidazole). Journal of Materials Chemistry, 18(5), 553-559. https://doi.org/10.1039/b716367n
Annenkov, Vadim V. ; Danilovtseva, Elena N. ; Likhoshway, Yelena V. ; Patwardhan, Siddharth V. ; Perry, Carole C. / Controlled stabilisation of silicic acid below pH 9 using poly(1-vinylimidazole). In: Journal of Materials Chemistry. 2008 ; Vol. 18, No. 5. pp. 553-559.
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Annenkov, VV, Danilovtseva, EN, Likhoshway, YV, Patwardhan, SV & Perry, CC 2008, 'Controlled stabilisation of silicic acid below pH 9 using poly(1-vinylimidazole)' Journal of Materials Chemistry, vol. 18, no. 5, pp. 553-559. https://doi.org/10.1039/b716367n

Controlled stabilisation of silicic acid below pH 9 using poly(1-vinylimidazole). / Annenkov, Vadim V.; Danilovtseva, Elena N.; Likhoshway, Yelena V.; Patwardhan, Siddharth V.; Perry, Carole C.

In: Journal of Materials Chemistry, Vol. 18, No. 5, 2008, p. 553-559.

Research output: Contribution to journalArticle

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T1 - Controlled stabilisation of silicic acid below pH 9 using poly(1-vinylimidazole)

AU - Annenkov, Vadim V.

AU - Danilovtseva, Elena N.

AU - Likhoshway, Yelena V.

AU - Patwardhan, Siddharth V.

AU - Perry, Carole C.

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AB - We show, for the first time, inhibition of silicic acid condensation over a wide range of pH, especially below 9 using certain molecular mass fractions of poly(1-vinylimidazole) (PVI). This is achieved by stabilisation of molybdate-active Si species, which are crucial to condensation and growth to form silica. The structure of the resulting composites depends on the molecular mass of the PVI chains. Long-chain macromolecules can ''encapsulate'' Si species giving rise to stable soluble complexes. Short PVI chains stimulate association of silica particles and at neutral pH precipitation occurs. Protonation of imidazole units in acidic pH results in dissolution of the precipitates. We believe that the results presented herein using PVI as a model system will help elucidate the mechanisms underpinning the molecular interactions between (bio) macromolecules and inorganic materials.

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KW - silicification

KW - viscosity

KW - complexes

KW - diatoms

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