Conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrole

Kai Zhang; Bernd Tieke; Filipe Vilela; Peter J. Skabara

doi:10.1002/marc.201100045

Conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrole

Kai Zhang, Bernd Tieke, Filipe Vilela, Peter J. Skabara

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

pi-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) . g(-1)

Original language	English
Pages (from-to)	825-830
Number of pages	6
Journal	Macromolecular Rapid Communications
Volume	32
Issue number	11
DOIs	https://doi.org/10.1002/marc.201100045
Publication status	Published - 1 Jun 2011

Keywords

conjugated polymers
diketopyrrolopyrrole
DPP
microporous materials
networks
ordered mesoporous materials
covalent organic frameworks
hydrogen storage materials
polymer solar cells
surface-area
intrinsic microporosity
highly luminescent
main-chain
adsorption
bandgap

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10.1002/marc.201100045

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title = "Conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrole",

abstract = "pi-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) . g(-1)",

keywords = "conjugated polymers, diketopyrrolopyrrole, DPP, microporous materials, networks, ordered mesoporous materials, covalent organic frameworks, hydrogen storage materials, polymer solar cells, surface-area, intrinsic microporosity, highly luminescent, main-chain, adsorption, bandgap",

author = "Kai Zhang and Bernd Tieke and Filipe Vilela and Skabara, {Peter J.}",

year = "2011",

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language = "English",

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AU - Zhang, Kai

AU - Tieke, Bernd

AU - Vilela, Filipe

AU - Skabara, Peter J.

PY - 2011/6/1

Y1 - 2011/6/1

N2 - pi-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) . g(-1)

AB - pi-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) . g(-1)

KW - conjugated polymers

KW - diketopyrrolopyrrole

KW - DPP

KW - microporous materials

KW - networks

KW - ordered mesoporous materials

KW - covalent organic frameworks

KW - hydrogen storage materials

KW - polymer solar cells

KW - surface-area

KW - intrinsic microporosity

KW - highly luminescent

KW - main-chain

KW - adsorption

KW - bandgap

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U2 - 10.1002/marc.201100045

DO - 10.1002/marc.201100045

M3 - Article

SN - 1022-1336

VL - 32

SP - 825

EP - 830

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 11

ER -

Conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrole

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Keywords

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Physical Organic Chemistry: Opportunities In Synthesis, Materials And Pharmaceuticals (Science And Innovation Award)

SELF ASSEMBLING CONJUGATED MACROMOLECULES FOR ORGANIC FIELD EFFECT TRANSISTORS AND SOLAR CELLS

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Conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrole

Abstract

Keywords

Access to Document

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Projects

Physical Organic Chemistry: Opportunities In Synthesis, Materials And Pharmaceuticals (Science And Innovation Award)

SELF ASSEMBLING CONJUGATED MACROMOLECULES FOR ORGANIC FIELD EFFECT TRANSISTORS AND SOLAR CELLS

Cite this