Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

Felipe Garcia; Robert J. Less; Mary McPartlin; Annette Michalski; Robert E. Mulvey; Vesal Naseri; Matthew L. Stead; Ana Moran de Vega; Dominic S. Wright

doi:10.1039/c0cc04483k

Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

Felipe Garcia, Robert J. Less, Mary McPartlin, Annette Michalski, Robert E. Mulvey, Vesal Naseri, Matthew L. Stead, Ana Moran de Vega, Dominic S. Wright

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li-4 center dot 3thf}(4)(mu(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li-4 sites has negligible effect on the structural parameters.

Original language	English
Pages (from-to)	1821-1823
Number of pages	3
Journal	Chemical Communications (London)
Volume	47
Issue number	6
Early online date	6 Dec 2010
DOIs	https://doi.org/10.1039/c0cc04483k
Publication status	Published - 2011

Keywords

crystal structures
metal
derivatives
clusters
dianion
amides

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10.1039/c0cc04483k

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title = "Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity",

abstract = "The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li-4 center dot 3thf}(4)(mu(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li-4 sites has negligible effect on the structural parameters.",

keywords = "crystal structures, metal, derivatives, clusters, dianion, amides",

author = "Felipe Garcia and Less, {Robert J.} and Mary McPartlin and Annette Michalski and Mulvey, {Robert E.} and Vesal Naseri and Stead, {Matthew L.} and {de Vega}, {Ana Moran} and Wright, {Dominic S.}",

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doi = "10.1039/c0cc04483k",

language = "English",

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pages = "1821--1823",

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T1 - Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

AU - Garcia, Felipe

AU - Less, Robert J.

AU - McPartlin, Mary

AU - Michalski, Annette

AU - Mulvey, Robert E.

AU - Naseri, Vesal

AU - Stead, Matthew L.

AU - de Vega, Ana Moran

AU - Wright, Dominic S.

PY - 2011

Y1 - 2011

N2 - The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li-4 center dot 3thf}(4)(mu(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li-4 sites has negligible effect on the structural parameters.

AB - The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li-4 center dot 3thf}(4)(mu(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li-4 sites has negligible effect on the structural parameters.

KW - crystal structures

KW - metal

KW - derivatives

KW - clusters

KW - dianion

KW - amides

UR - http://www.scopus.com/inward/record.url?scp=79251529890&partnerID=8YFLogxK

U2 - 10.1039/c0cc04483k

DO - 10.1039/c0cc04483k

M3 - Article

SN - 0009-241X

VL - 47

SP - 1821

EP - 1823

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 6

ER -

Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

Abstract

Keywords

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