Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

Felipe Garcia, Robert J. Less, Mary McPartlin, Annette Michalski, Robert E. Mulvey, Vesal Naseri, Matthew L. Stead, Ana Moran de Vega, Dominic S. Wright

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li-4 center dot 3thf}(4)(mu(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li-4 sites has negligible effect on the structural parameters.

LanguageEnglish
Pages1821-1823
Number of pages3
JournalChemical Communications (London)
Volume47
Issue number6
Early online date6 Dec 2010
DOIs
Publication statusPublished - 2011

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Keywords

  • crystal structures
  • metal
  • derivatives
  • clusters
  • dianion
  • amides

Cite this

Garcia, Felipe ; Less, Robert J. ; McPartlin, Mary ; Michalski, Annette ; Mulvey, Robert E. ; Naseri, Vesal ; Stead, Matthew L. ; de Vega, Ana Moran ; Wright, Dominic S. / Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity. In: Chemical Communications (London). 2011 ; Vol. 47, No. 6. pp. 1821-1823.
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Garcia, F, Less, RJ, McPartlin, M, Michalski, A, Mulvey, RE, Naseri, V, Stead, ML, de Vega, AM & Wright, DS 2011, 'Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity' Chemical Communications (London), vol. 47, no. 6, pp. 1821-1823. https://doi.org/10.1039/c0cc04483k

Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity. / Garcia, Felipe; Less, Robert J.; McPartlin, Mary; Michalski, Annette; Mulvey, Robert E.; Naseri, Vesal; Stead, Matthew L.; de Vega, Ana Moran; Wright, Dominic S.

In: Chemical Communications (London), Vol. 47, No. 6, 2011, p. 1821-1823.

Research output: Contribution to journalArticle

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T1 - Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

AU - Garcia, Felipe

AU - Less, Robert J.

AU - McPartlin, Mary

AU - Michalski, Annette

AU - Mulvey, Robert E.

AU - Naseri, Vesal

AU - Stead, Matthew L.

AU - de Vega, Ana Moran

AU - Wright, Dominic S.

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KW - crystal structures

KW - metal

KW - derivatives

KW - clusters

KW - dianion

KW - amides

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T2 - Chemical Communications (London)

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