Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

Felipe Garcia, Robert J. Less, Mary McPartlin, Annette Michalski, Robert E. Mulvey, Vesal Naseri, Matthew L. Stead, Ana Moran de Vega, Dominic S. Wright

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Abstract

The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li-4 center dot 3thf}(4)(mu(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li-4 sites has negligible effect on the structural parameters.

Original languageEnglish
Pages (from-to)1821-1823
Number of pages3
JournalChemical Communications (London)
Volume47
Issue number6
Early online date6 Dec 2010
DOIs
Publication statusPublished - 2011

Keywords

  • crystal structures
  • metal
  • derivatives
  • clusters
  • dianion
  • amides

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    Garcia, F., Less, R. J., McPartlin, M., Michalski, A., Mulvey, R. E., Naseri, V., Stead, M. L., de Vega, A. M., & Wright, D. S. (2011). Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity. Chemical Communications (London), 47(6), 1821-1823. https://doi.org/10.1039/c0cc04483k