Projects per year
Abstract
Recent developments in experimental and computational chemistry have identified a rapidly growing class of nucleophilic aromatic substitutions that proceed by concerted (cS NAr) rather than classical, two-step, S NAr mechanisms. Whereas traditional S NAr reactions require substantial activation of the aromatic ring by electron-withdrawing substituents, such activating groups are not mandatory in the concerted pathways.
Original language | English |
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Pages (from-to) | 16368-16388 |
Number of pages | 21 |
Journal | Angewandte Chemie International Edition |
Volume | 58 |
Issue number | 46 |
Early online date | 16 Apr 2019 |
DOIs | |
Publication status | Published - 11 Nov 2019 |
Keywords
- nucleophilic aromatic substitutions
- substitution reactions
- electron transfer
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Dive into the research topics of 'Concerted nucleophilic aromatic substitution reactions'. Together they form a unique fingerprint.Projects
- 1 Finished
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Industrial Case Account 2015 | Smith, Andrew
Murphy, J., Nelson, D. & Smith, A.
EPSRC (Engineering and Physical Sciences Research Council)
1/10/15 → 5/03/20
Project: Research Studentship - Internally Allocated
Datasets
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Data for: "Computational Study on the Boundary Between the Concerted and Stepwise Mechanism of Bimolecular SNAr Reactions" (2nd Revision)
Tuttle, T. (Creator), Rohrbach, S. (Creator) & Murphy, J. (Contributor), University of Strathclyde, 8 Jun 2020
DOI: 10.15129/254ecae8-9c72-4bb9-9319-b16eada94f9c
Dataset
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Data for: "Concerted and Stepwise Mechanistic Domain of SNAr Reactions"
Rohrbach, S. (Creator), Murphy, J. (Contributor) & Tuttle, T. (Contributor), University of Strathclyde, 19 Feb 2020
DOI: 10.15129/289a4204-12ff-4ead-9490-d11fac96f645
Dataset
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Data for: "Concerted and Stepwise Mechanistic Domain of SNAr Reactions" (Revised)
Rohrbach, S. (Creator), Murphy, J. (Contributor) & Tuttle, T. (Contributor), University of Strathclyde, 1 May 2020
DOI: 10.15129/4c87d271-4469-4ed5-98dd-4d1d4b46e237
Dataset