Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O

Dale Cave, Fiona Coomer, Eduardo Molinos, Hans-Henning Klauss, Paul T Wood

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

In the title iron phosphonate compounds, triangles and hexagons fuse together to generate a maple leaf lattice (see polyhedral representation; green Fe, purple P). This lattice is a new type of topologically frustrated antiferromagnetic network. Exotic forms of magnetic behavior are often encountered in such frustrated materials.
LanguageEnglish
Pages803-806
Number of pages4
JournalAngewandte Chemie International Edition
Volume45
Issue number5
DOIs
Publication statusPublished - 2006

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Iron Compounds
Acer
Organophosphonates

Keywords

  • geometric frustration
  • hydrothermal synthesis
  • iron magnetic properties
  • phosphonates

Cite this

Cave, Dale ; Coomer, Fiona ; Molinos, Eduardo ; Klauss, Hans-Henning ; Wood, Paul T. / Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O. In: Angewandte Chemie International Edition. 2006 ; Vol. 45, No. 5. pp. 803-806.
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abstract = "In the title iron phosphonate compounds, triangles and hexagons fuse together to generate a maple leaf lattice (see polyhedral representation; green Fe, purple P). This lattice is a new type of topologically frustrated antiferromagnetic network. Exotic forms of magnetic behavior are often encountered in such frustrated materials.",
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Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O. / Cave, Dale; Coomer, Fiona; Molinos, Eduardo; Klauss, Hans-Henning; Wood, Paul T.

In: Angewandte Chemie International Edition, Vol. 45, No. 5, 2006, p. 803-806.

Research output: Contribution to journalArticle

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AU - Molinos, Eduardo

AU - Klauss, Hans-Henning

AU - Wood, Paul T

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KW - hydrothermal synthesis

KW - iron magnetic properties

KW - phosphonates

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JF - Angewandte Chemie International Edition

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