Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O

Dale Cave; Fiona Coomer; Eduardo Molinos; Hans-Henning Klauss; Paul T Wood

doi:10.1002/anie.200502847

Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O

Dale Cave, Fiona Coomer, Eduardo Molinos, Hans-Henning Klauss, Paul T Wood

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

In the title iron phosphonate compounds, triangles and hexagons fuse together to generate a maple leaf lattice (see polyhedral representation; green Fe, purple P). This lattice is a new type of topologically frustrated antiferromagnetic network. Exotic forms of magnetic behavior are often encountered in such frustrated materials.

Original language	English
Pages (from-to)	803-806
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	45
Issue number	5
DOIs	https://doi.org/10.1002/anie.200502847
Publication status	Published - 2006

Keywords

geometric frustration
hydrothermal synthesis
iron magnetic properties
phosphonates

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title = "Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O",

abstract = "In the title iron phosphonate compounds, triangles and hexagons fuse together to generate a maple leaf lattice (see polyhedral representation; green Fe, purple P). This lattice is a new type of topologically frustrated antiferromagnetic network. Exotic forms of magnetic behavior are often encountered in such frustrated materials.",

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AU - Cave, Dale

AU - Coomer, Fiona

AU - Molinos, Eduardo

AU - Klauss, Hans-Henning

AU - Wood, Paul T

PY - 2006

Y1 - 2006

N2 - In the title iron phosphonate compounds, triangles and hexagons fuse together to generate a maple leaf lattice (see polyhedral representation; green Fe, purple P). This lattice is a new type of topologically frustrated antiferromagnetic network. Exotic forms of magnetic behavior are often encountered in such frustrated materials.

AB - In the title iron phosphonate compounds, triangles and hexagons fuse together to generate a maple leaf lattice (see polyhedral representation; green Fe, purple P). This lattice is a new type of topologically frustrated antiferromagnetic network. Exotic forms of magnetic behavior are often encountered in such frustrated materials.

KW - geometric frustration

KW - hydrothermal synthesis

KW - iron magnetic properties

KW - phosphonates

U2 - 10.1002/anie.200502847

DO - 10.1002/anie.200502847

M3 - Article

VL - 45

SP - 803

EP - 806

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 5

ER -

Compounds with the “Maple Leaf” Lattice: Synthesis, Structure, and Magnetism of Mx[Fe(O2CCH2)2NCH2PO3]6⋅n H2O

Abstract

Keywords

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