Colloidal quantum dot nanocomposites for visible wavelength conversion of modulated optical signals

Nicolas Laurand, Benoit Jack Eloi Guilhabert, Jonathan Mckendry, A. Kelly, B. Rae, David Massoubre, Zheng Gong, Erdan Gu, R.K. Henderson, Martin Dawson

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

We report on the steady-state and optical modulation characteristics of a luminescence down-converting colloidal quantum dot/polyimide nanocomposite system suitable for integration with gallium nitride optoelectronics. The approach provides solution-processable and environmentally stable composite materials whose optical conversion and intrinsic modulation properties were evaluated at wavelengths from 535 to 624 nm. A nanocomposite for white-light generation upon excitation and mixing with 450-nm light was also obtained by blending colloidal quantum dots of different sizes in the same matrix. The forward external quantum efficiencies of the resulting nanocomposites were found to depend on the wavelength and can be as high as 33%. Optical modulation bandwidth above 25 MHz, which is an order of magnitude higher than for typical phosphor-based color-converters for GaN LEDs, and wavelength-converted data with an open-eye diagram at 25 Mb/s are demonstrated under external gallium nitride light-emitting diode excitation. These modulation characteristics are correlated with carrier lifetimes. This work provides guideline parameters and creates a possible path to integrated hybrid visible light sources for scientific and communications application
LanguageEnglish
Pages250-260
Number of pages11
JournalOptical Materials
Volume2
Issue number3
DOIs
Publication statusPublished - 13 Feb 2012

Fingerprint

Optical frequency conversion
Semiconductor quantum dots
optical communication
Nanocomposites
Gallium nitride
nanocomposites
Light modulation
light modulation
gallium nitrides
quantum dots
modulation
Wavelength
Light emitting diodes
light emitting diodes
Modulation
wavelengths
Carrier lifetime
carrier lifetime
Quantum efficiency
polyimides

Keywords

  • quantum dot nanocomposites
  • wavelength conversion
  • modulated optical signals
  • optics

Cite this

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abstract = "We report on the steady-state and optical modulation characteristics of a luminescence down-converting colloidal quantum dot/polyimide nanocomposite system suitable for integration with gallium nitride optoelectronics. The approach provides solution-processable and environmentally stable composite materials whose optical conversion and intrinsic modulation properties were evaluated at wavelengths from 535 to 624 nm. A nanocomposite for white-light generation upon excitation and mixing with 450-nm light was also obtained by blending colloidal quantum dots of different sizes in the same matrix. The forward external quantum efficiencies of the resulting nanocomposites were found to depend on the wavelength and can be as high as 33{\%}. Optical modulation bandwidth above 25 MHz, which is an order of magnitude higher than for typical phosphor-based color-converters for GaN LEDs, and wavelength-converted data with an open-eye diagram at 25 Mb/s are demonstrated under external gallium nitride light-emitting diode excitation. These modulation characteristics are correlated with carrier lifetimes. This work provides guideline parameters and creates a possible path to integrated hybrid visible light sources for scientific and communications application",
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Colloidal quantum dot nanocomposites for visible wavelength conversion of modulated optical signals. / Laurand, Nicolas; Guilhabert, Benoit Jack Eloi; Mckendry, Jonathan; Kelly, A.; Rae, B.; Massoubre, David; Gong, Zheng; Gu, Erdan; Henderson, R.K.; Dawson, Martin.

In: Optical Materials, Vol. 2, No. 3, 13.02.2012, p. 250-260.

Research output: Contribution to journalArticle

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