TY - JOUR
T1 - Collision statistics, thermodynamics, and transport coefficients of hard hyperspheres in three, four, and five dimensions
AU - Lue, L.
PY - 2005/1/22
Y1 - 2005/1/22
N2 - The collision statistics of hard hyperspheres are investigated. An exact, analytical formula is developed for the distribution of speeds of a sphere on collision, which is shown to be related to the average time between collisions for a sphere with a particular velocity. In addition, the relationship between the collision rate and the compressibility factor is generalized to arbitrary dimensions. Molecular dynamics simulations are performed for d = 3, 4, and 5 dimensional hard-hypersphere fluids. From these simulations, the equation of state of these systems, the self-diffusion coefficient, the shear viscosity, and the thermal conductivity are determined as a function of density. Various aspects of the collision statistics and their dependence on the density and dimensionality of the system are also studied.
AB - The collision statistics of hard hyperspheres are investigated. An exact, analytical formula is developed for the distribution of speeds of a sphere on collision, which is shown to be related to the average time between collisions for a sphere with a particular velocity. In addition, the relationship between the collision rate and the compressibility factor is generalized to arbitrary dimensions. Molecular dynamics simulations are performed for d = 3, 4, and 5 dimensional hard-hypersphere fluids. From these simulations, the equation of state of these systems, the self-diffusion coefficient, the shear viscosity, and the thermal conductivity are determined as a function of density. Various aspects of the collision statistics and their dependence on the density and dimensionality of the system are also studied.
KW - collision statistics
KW - thermodynamics
KW - hard hyperspheres
UR - http://jcp.aip.org/resource/1/jcpsa6/v122/i4/p044513_s1?isAuthorized=no
U2 - 10.1063/1.1834498
DO - 10.1063/1.1834498
M3 - Article
SN - 0021-9606
VL - 122
SP - 044513
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
ER -