cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II)

A.R. Kennedy; S.W. Sloss; M.D. Spicer

doi:10.1107/S0108270196014229

cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II)

A.R. Kennedy, S.W. Sloss, M.D. Spicer

Pure And Applied Chemistry

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

The formal pseudo-octahedral coordination around the Ni II atom in the title complex, [Ni(NO3)2(OPCy3)e], places the OPCy3 ligands (CI8H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.

Original language	English
Pages (from-to)	292-294
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	53
Issue number	3
DOIs	https://doi.org/10.1107/S0108270196014229
Publication status	Published - Mar 1997

Keywords

pseudo-octahedral
bidentate
tetrahedral

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10.1107/S0108270196014229

http://dx.doi.org/10.1107/S0108270196014229

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title = "cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II)",

abstract = "The formal pseudo-octahedral coordination around the Ni II atom in the title complex, [Ni(NO3)2(OPCy3)e], places the OPCy3 ligands (CI8H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.",

keywords = "pseudo-octahedral, bidentate, tetrahedral",

author = "A.R. Kennedy and S.W. Sloss and M.D. Spicer",

year = "1997",

month = mar,

doi = "10.1107/S0108270196014229",

language = "English",

volume = "53",

pages = "292--294",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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TY - JOUR

T1 - cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II)

AU - Kennedy, A.R.

AU - Sloss, S.W.

AU - Spicer, M.D.

PY - 1997/3

Y1 - 1997/3

N2 - The formal pseudo-octahedral coordination around the Ni II atom in the title complex, [Ni(NO3)2(OPCy3)e], places the OPCy3 ligands (CI8H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.

AB - The formal pseudo-octahedral coordination around the Ni II atom in the title complex, [Ni(NO3)2(OPCy3)e], places the OPCy3 ligands (CI8H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.

KW - pseudo-octahedral

KW - bidentate

KW - tetrahedral

UR - http://dx.doi.org/10.1107/S0108270196014229

U2 - 10.1107/S0108270196014229

DO - 10.1107/S0108270196014229

M3 - Article

VL - 53

SP - 292

EP - 294

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 3

ER -

cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II)

Abstract

Keywords

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