cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II)

A.R. Kennedy, S.W. Sloss, M.D. Spicer

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The formal pseudo-octahedral coordination around the Ni II atom in the title complex, [Ni(NO3)2(OPCy3)e], places the OPCy3 ligands (CI8H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.
LanguageEnglish
Pages292-294
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume53
Issue number3
DOIs
Publication statusPublished - Mar 1997

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Nickel
Oxides
Conformations
Ligands
Atoms
nickel monoxide

Keywords

  • pseudo-octahedral
  • bidentate
  • tetrahedral

Cite this

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title = "cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II)",
abstract = "The formal pseudo-octahedral coordination around the Ni II atom in the title complex, [Ni(NO3)2(OPCy3)e], places the OPCy3 ligands (CI8H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.",
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author = "A.R. Kennedy and S.W. Sloss and M.D. Spicer",
year = "1997",
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journal = "Acta Crystallographica Section C: Crystal Structure Communications",
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cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II). / Kennedy, A.R.; Sloss, S.W.; Spicer, M.D.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 53, No. 3, 03.1997, p. 292-294.

Research output: Contribution to journalArticle

TY - JOUR

T1 - cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II)

AU - Kennedy, A.R.

AU - Sloss, S.W.

AU - Spicer, M.D.

PY - 1997/3

Y1 - 1997/3

N2 - The formal pseudo-octahedral coordination around the Ni II atom in the title complex, [Ni(NO3)2(OPCy3)e], places the OPCy3 ligands (CI8H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.

AB - The formal pseudo-octahedral coordination around the Ni II atom in the title complex, [Ni(NO3)2(OPCy3)e], places the OPCy3 ligands (CI8H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.

KW - pseudo-octahedral

KW - bidentate

KW - tetrahedral

UR - http://dx.doi.org/10.1107/S0108270196014229

U2 - 10.1107/S0108270196014229

DO - 10.1107/S0108270196014229

M3 - Article

VL - 53

SP - 292

EP - 294

JO - Acta Crystallographica Section C: Crystal Structure Communications

T2 - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 3

ER -