catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]

Alan Kennedy; Robert Mulvey; Charles O'Hara; Stuart Robertson; Gemma Robertson

doi:10.1107/S1600536812045126

catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]

Alan Kennedy, Robert Mulvey, Charles O'Hara, Stuart Robertson, Gemma Robertson

Pure And Applied Chemistry

Research output: Contribution to journal › Article

8 Citations (Scopus)

Abstract

The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.

Original language	English
Article number	m1468
Number of pages	9
Journal	Acta Crystallographica Section E: Structure Reports
Volume	E68
Issue number	12
DOIs	https://doi.org/10.1107/S1600536812045126
Publication status	Published - Dec 2012

Keywords

crystallographically
polymers

Access to Document

10.1107/S1600536812045126

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Projects

3 Finished

Chiral Concepts in s-Block Metal Amide Chemistry

O'Hara, C.

EPSRC (Engineering and Physical Sciences Research Council)

1/10/11 → 30/09/16

Project: Research Fellowship

MIXED-METAL MOLECULAR SYNERGY (WOLFSON MERIT AWARD)

Mulvey, R.

Royal Society

1/04/09 → 31/03/14

Project: Research

EXPLOITING SYNTHETIC AND STRUCTURAL SYNERGISM IN ALKALI-METAL-MEDIATED ORGANOTRANSITIONMETALLATION (AMMO)

Mulvey, R. & Kennedy, A.

EPSRC (Engineering and Physical Sciences Research Council)

1/10/08 → 31/03/12

Project: Research

Equipment

x-ray diffractometer

Alan Kennedy (Manager)

Pure And Applied Chemistry

Facility/equipment: Equipment

Cite this

Kennedy, A., Mulvey, R., O'Hara, C., Robertson, S., & Robertson, G. (2012). catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]. Acta Crystallographica Section E: Structure Reports, E68(12), [m1468]. https://doi.org/10.1107/S1600536812045126

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title = "catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]",

abstract = "The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.",

keywords = "crystallographically, polymers",

author = "Alan Kennedy and Robert Mulvey and Charles O'Hara and Stuart Robertson and Gemma Robertson",

year = "2012",

month = dec,

doi = "10.1107/S1600536812045126",

language = "English",

volume = "E68",

journal = "Acta Crystallographica Section E: Structure Reports",

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T1 - catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]

AU - Kennedy, Alan

AU - Mulvey, Robert

AU - O'Hara, Charles

AU - Robertson, Stuart

AU - Robertson, Gemma

PY - 2012/12

Y1 - 2012/12

N2 - The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.

AB - The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.

KW - crystallographically

KW - polymers

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DO - 10.1107/S1600536812045126

M3 - Article

VL - E68

JO - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

SN - 1600-5368

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