catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]

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8 Citations (Scopus)

Abstract

The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.
LanguageEnglish
Article numberm1468
Number of pages9
JournalActa Crystallographica Section E: Structure Reports
VolumeE68
Issue number12
DOIs
Publication statusPublished - Dec 2012

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Diamines
diamines
coordination polymers
Dimers
Polymers
Sodium
Ligands
dimers
sodium
ligands
rings
N,N,N',N'-tetramethylethylenediamine
Direction compound

Keywords

  • crystallographically
  • polymers

Cite this

@article{e59c1bd6bc064d0c9371018c4af4cc1d,
title = "catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]",
abstract = "The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.",
keywords = "crystallographically, polymers",
author = "Alan Kennedy and Robert Mulvey and Charles O'Hara and Stuart Robertson and Gemma Robertson",
year = "2012",
month = "12",
doi = "10.1107/S1600536812045126",
language = "English",
volume = "E68",
journal = "Acta Crystallographica Section E: Structure Reports",
issn = "1600-5368",
number = "12",

}

TY - JOUR

T1 - catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]

AU - Kennedy, Alan

AU - Mulvey, Robert

AU - O'Hara, Charles

AU - Robertson, Stuart

AU - Robertson, Gemma

PY - 2012/12

Y1 - 2012/12

N2 - The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.

AB - The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.

KW - crystallographically

KW - polymers

UR - http://www.scopus.com/inward/record.url?scp=84870954597&partnerID=8YFLogxK

UR - http://journals.iucr.org/e/issues/2012/12/00/issconts.html

U2 - 10.1107/S1600536812045126

DO - 10.1107/S1600536812045126

M3 - Article

VL - E68

JO - Acta Crystallographica Section E: Structure Reports

T2 - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

SN - 1600-5368

IS - 12

M1 - m1468

ER -