Abstract
| Language | English |
|---|---|
| Article number | m1468 |
| Number of pages | 9 |
| Journal | Acta Crystallographica Section E: Structure Reports |
| Volume | E68 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - Dec 2012 |
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Keywords
- crystallographically
- polymers
Cite this
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catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]. / Kennedy, Alan; Mulvey, Robert; O'Hara, Charles; Robertson, Stuart; Robertson, Gemma.
In: Acta Crystallographica Section E: Structure Reports, Vol. E68, No. 12, m1468, 12.2012.Research output: Contribution to journal › Article
TY - JOUR
T1 - catena-Poly[sodium-2-(N,N,N',N'-tetramethylethane-1,2-diamine)-2N:N'-sodium-bis[2-bis(trimethylsilyl)azanido-2N:N]]
AU - Kennedy, Alan
AU - Mulvey, Robert
AU - O'Hara, Charles
AU - Robertson, Stuart
AU - Robertson, Gemma
PY - 2012/12
Y1 - 2012/12
N2 - The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.
AB - The title compound, [Na2(C6H18NSi2)2(C6H16N2)]n, was found to consist of dimeric [Na(NSiMe3)2] units with crystallographically imposed centrosymmetry based upon four-membered NaNNaN rings. The dimers are bridged by N,N,N',N'-tetramethylethylenediamine ligands, which act in an unusual extended non-chelating coordination mode. This gives a one-dimensional coordination polymer that extends parallel to the a-axis direction.
KW - crystallographically
KW - polymers
UR - http://www.scopus.com/inward/record.url?scp=84870954597&partnerID=8YFLogxK
UR - http://journals.iucr.org/e/issues/2012/12/00/issconts.html
U2 - 10.1107/S1600536812045126
DO - 10.1107/S1600536812045126
M3 - Article
VL - E68
JO - Acta Crystallographica Section E: Structure Reports
T2 - Acta Crystallographica Section E: Structure Reports
JF - Acta Crystallographica Section E: Structure Reports
SN - 1600-5368
IS - 12
M1 - m1468
ER -