Abstract
The asymmetric unit of the title compound, [Ag( NO2)-( C14H14N4)](n), contains half of the repeating formula unit (Z ' = 1/2). The Ag-I ion lies on a twofold rotation axis. The primary structure consists of a one-dimensional coordination polymer formed by the Ag-I ions and the bipyridyl azine ligand in which there is an inversion center at the mid- point of the N-N bond. The nitrite anion interacts with the Ag-I ion through a chelating mu(2) interaction involving both O atoms. In the crystal, the coordination chains are parallel and interact through Ag center dot center dot center dot pi [3.220 (2) angstrom] and pi-pi [3.489 (3) angstrom] interactions.
Original language | English |
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Pages (from-to) | M1138-U1193 |
Number of pages | 9 |
Journal | Acta Crystallographica Section E: Structure Reports |
Volume | 67 |
DOIs | |
Publication status | Published - Aug 2011 |
Keywords
- complexes
- ligands