Carriers multiplication in neighboring surfactant-free silicon nanocrystals produced by 3D-surface engineering in liquid medium

Vladimir Svrcek, Davide Mariotti, Koiji Matsubara, Michio Kondo

Research output: Chapter in Book/Report/Conference proceedingConference contribution book

1 Citation (Scopus)

Abstract

Carriers multiplication in silicon nanocrystals (Si-ncs) in a one promising eefect to considerably enhance conversion efficiency of solar cells that can overcome theoretical limits. A close proximity of Si-ncs is an essential factor for carrier multiplication due to the separated quantum cutting effect. In this study we present results on investigation of 3-dimensional (3D) surface engineering of Si-ncs directly in water. Thus at the same time allow close proximity Si-ncs without of using any surfactant. The approach is based on ns laser treatment of Si-ncs dispersed in liquid solution. We explore the excitation wavelength dependence of photoluminescence quantum yield (ratio of the number of emitted and absorbed photons) for Si-ncs as prepared and surface engineered by ns laser processing. Our results suggest that close proximity of Si-ncs in spherical particles induced by laser processing might enhance also carriers multiplication.
Original languageEnglish
Title of host publication2012 38th IEEE Photovoltaic Specialists Conference
Place of PublicationPiscataway, NJ
PublisherIEEE
Pages101-104
Number of pages4
ISBN (Electronic)9781467300667
ISBN (Print)9781467300643
DOIs
Publication statusPublished - 4 Oct 2012
Event2012 38th IEEE Photovoltaic Specialists Conference - Austin, TX, USA
Duration: 3 Jun 20128 Jun 2012

Conference

Conference2012 38th IEEE Photovoltaic Specialists Conference
Period3/06/128/06/12

Keywords

  • silicon
  • nanocrystals
  • surface emitting lasers
  • laser excitation
  • surface engineering
  • surface treatment
  • photonics

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