Carbonate caprock-brine-CO2 interaction: alteration of hydromechanical properties

Caprocks play a crucial role in geological storage of CO2 by preventing the escape of CO2 and thus trapping CO2 into underlying porous reservoirs. An evaluation of interaction-induced alteration of hydromechanical properties of caprocks are essential to better assess the leaking risk and injection-induced rock instability, and thus ensuring a long-term viability of geological CO2 storage. We study the changes in nanopores, elastic velocities and mechanical responses of a carbonate caprock due to rock-water/brine-CO2 interaction (CO2 pressure ~ 12 MPa; 50 ℃). Before the interaction, the total and accessible porosities are 1.6% and 0.6%, respectively, as characterized by the Small Angle Neutron Scattering (SANS) technique. SANS results show that the total porosity of the carbonate caprock increases apparently due to rock-brine-CO2 interaction and the increasing rate rises as brine concentration increases (2.2% for 0M NaCl, 2.6% for 1M NaCl, and 2.7% for 4M NaCl). The increase total porosity is due to the dissolution of calcite which tends to enlarge accessible pores (by 0.8%-1.2%) while slightly decrease the inaccessible pores (by 0.1%-0.2%). Under CO2-acidified water environment, P- and S-wave velocities (5536.7 m/s and 2699.7 m/s) of a core sample containing natural fractures decreases by 8.5% and 8.1% respectively, while both P- and S-wave velocities (6074.1 m/s and 3858.8 m/s) for a intact sample show only ~0.5% decreases. The interaction also causes more than 50% degradation of the uniaxial compressive strength for the core sample with natural fractures.