Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure

L. E. Connor, C. A. Morrison, I.D.H. Oswald, C.R. Pulham, M. R. Warren

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Abstract

A carbon dioxide and nitrous oxide solid solution has been captured in a diamond anvil cell following the thermal decomposition of 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX) at high temperatures and pressures. This is the first time a carbon dioxide binary solid has been observed at high pressure. This observation has stimulated low temperature crystallographic studies of this binary system using recently developed gas absorption apparatus and computational modelling.
Original languageEnglish
Pages (from-to)4872-4878
Number of pages7
JournalChemical Science
Volume8
Issue number7
Early online date4 May 2017
DOIs
Publication statusPublished - 1 Jul 2017

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Keywords

  • carbon dioxide
  • nitrous oxide
  • binary crystal
  • high pressure
  • computational chemistry
  • low temperature

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