Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes: reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order

Guillaume Schweicher; Vincent Lemaur; Claude Niebel; Christian Ruzié; Ying Diao; Osamu Goto; Wen-Ya Lee; Yeongin Kim; Jean-Baptiste Arlin; Jolanta Karpinska; Alan R. Kennedy; Sean R. Parkin; Yoann Olivier; Stefan C. B. Mannsfeld; Jérôme Cornil; Yves H. Geerts; Zhenan Bao

doi:10.1002/adma.201500322

Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes: reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order

Guillaume Schweicher, Vincent Lemaur, Claude Niebel, Christian Ruzié, Ying Diao, Osamu Goto, Wen-Ya Lee, Yeongin Kim, Jean-Baptiste Arlin, Jolanta Karpinska, Alan R. Kennedy, Sean R. Parkin, Yoann Olivier, Stefan C. B. Mannsfeld, Jérôme Cornil, Yves H. Geerts, Zhenan Bao

Pure And Applied Chemistry

Research output: Contribution to journal › Article

101 Citations (Scopus)

95 Downloads (Pure)

Abstract

A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm(2) V(-1) s(-1) .

Original language	English
Pages (from-to)	3066-3072
Number of pages	7
Journal	Advanced Materials
Volume	27
Issue number	19
Early online date	9 Apr 2015
DOIs	https://doi.org/10.1002/adma.201500322
Publication status	Published - 20 May 2015

Keywords

high mobility
organic semiconductor
organic transistor
single crystal

Access to Document

10.1002/adma.201500322

Schweicher-etal-AM-2015-Bulky-end-capped-1benzothieno-3-2-b-benzothiophenes-reaching-high-mobility-organicAccepted author manuscript, 3.52 MB

http://onlinelibrary.wiley.com/wol1/doi/10.1002/adma.201500322/abstract

Fingerprint Dive into the research topics of 'Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes: reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order'. Together they form a unique fingerprint.

Profiles

Alan Kennedy

a.r.kennedy@strath.ac.uk

Pure And Applied Chemistry - Reader

Person: Academic

Equipment

x-ray diffractometer

Alan Kennedy (Manager)

Pure And Applied Chemistry

Facility/equipment: Equipment

Cite this

Schweicher, G., Lemaur, V., Niebel, C., Ruzié, C., Diao, Y., Goto, O., Lee, W-Y., Kim, Y., Arlin, J-B., Karpinska, J., Kennedy, A. R., Parkin, S. R., Olivier, Y., Mannsfeld, S. C. B., Cornil, J., Geerts, Y. H., & Bao, Z. (2015). Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes: reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order. Advanced Materials, 27(19), 3066-3072. https://doi.org/10.1002/adma.201500322

Schweicher, Guillaume ; Lemaur, Vincent ; Niebel, Claude ; Ruzié, Christian ; Diao, Ying ; Goto, Osamu ; Lee, Wen-Ya ; Kim, Yeongin ; Arlin, Jean-Baptiste ; Karpinska, Jolanta ; Kennedy, Alan R. ; Parkin, Sean R. ; Olivier, Yoann ; Mannsfeld, Stefan C. B. ; Cornil, Jérôme ; Geerts, Yves H. ; Bao, Zhenan. / Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes : reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order. In: Advanced Materials. 2015 ; Vol. 27, No. 19. pp. 3066-3072.

@article{b59fb132747c4bdaa165db27fa439042,

title = "Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes: reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order",

abstract = "A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm(2) V(-1) s(-1) .",

keywords = "high mobility, organic semiconductor, organic transistor, single crystal",

author = "Guillaume Schweicher and Vincent Lemaur and Claude Niebel and Christian Ruzi{\'e} and Ying Diao and Osamu Goto and Wen-Ya Lee and Yeongin Kim and Jean-Baptiste Arlin and Jolanta Karpinska and Kennedy, {Alan R.} and Parkin, {Sean R.} and Yoann Olivier and Mannsfeld, {Stefan C. B.} and J{\'e}r{\^o}me Cornil and Geerts, {Yves H.} and Zhenan Bao",

note = "This is the accepted version of the following article: Schweicher, G., Lemaur, V., Niebel, C., Ruzi{\'e}, C., Diao, Y., Goto, O., ... Bao, Z. (2015). Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes: reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order. Advanced Materials. 10.1002/adma.201500322, which has been published in final form at http://onlinelibrary.wiley.com/wol1/doi/10.1002/adma.201500322/abstract. ",

year = "2015",

month = may,

day = "20",

doi = "10.1002/adma.201500322",

language = "English",

volume = "27",

pages = "3066--3072",

journal = "Advanced Materials",

issn = "1521-4095",

number = "19",

}

Schweicher, G, Lemaur, V, Niebel, C, Ruzié, C, Diao, Y, Goto, O, Lee, W-Y, Kim, Y, Arlin, J-B, Karpinska, J, Kennedy, AR, Parkin, SR, Olivier, Y, Mannsfeld, SCB, Cornil, J, Geerts, YH & Bao, Z 2015, 'Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes: reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order', Advanced Materials, vol. 27, no. 19, pp. 3066-3072. https://doi.org/10.1002/adma.201500322

Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes : reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order. / Schweicher, Guillaume; Lemaur, Vincent; Niebel, Claude; Ruzié, Christian; Diao, Ying; Goto, Osamu; Lee, Wen-Ya; Kim, Yeongin; Arlin, Jean-Baptiste; Karpinska, Jolanta; Kennedy, Alan R.; Parkin, Sean R.; Olivier, Yoann; Mannsfeld, Stefan C. B.; Cornil, Jérôme; Geerts, Yves H.; Bao, Zhenan.

In: Advanced Materials, Vol. 27, No. 19, 20.05.2015, p. 3066-3072.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes

T2 - reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order

AU - Schweicher, Guillaume

AU - Lemaur, Vincent

AU - Niebel, Claude

AU - Ruzié, Christian

AU - Diao, Ying

AU - Goto, Osamu

AU - Lee, Wen-Ya

AU - Kim, Yeongin

AU - Arlin, Jean-Baptiste

AU - Karpinska, Jolanta

AU - Kennedy, Alan R.

AU - Parkin, Sean R.

AU - Olivier, Yoann

AU - Mannsfeld, Stefan C. B.

AU - Cornil, Jérôme

AU - Geerts, Yves H.

AU - Bao, Zhenan

N1 - This is the accepted version of the following article: Schweicher, G., Lemaur, V., Niebel, C., Ruzié, C., Diao, Y., Goto, O., ... Bao, Z. (2015). Bulky end-capped [1]benzothieno[3,2-b]benzothiophenes: reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state order. Advanced Materials. 10.1002/adma.201500322, which has been published in final form at http://onlinelibrary.wiley.com/wol1/doi/10.1002/adma.201500322/abstract.

PY - 2015/5/20

Y1 - 2015/5/20

N2 - A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm(2) V(-1) s(-1) .

AB - A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm(2) V(-1) s(-1) .

KW - high mobility

KW - organic semiconductor

KW - organic transistor

KW - single crystal

UR - http://onlinelibrary.wiley.com/wol1/doi/10.1002/adma.201500322/abstract

U2 - 10.1002/adma.201500322

DO - 10.1002/adma.201500322

M3 - Article

C2 - 25855909

VL - 27

SP - 3066

EP - 3072

JO - Advanced Materials

JF - Advanced Materials

SN - 1521-4095

IS - 19

ER -