Boosting axiality in stable high-coordinate Dy(iii) single-molecule magnets

Angelos B. Canaj; Mukesh Kumar Singh; Emma Regincos Marti; Marko Damjanovic; Claire Wilson; Oscar Cespedes; Wolfgang Wernsdorfer; Gopalan Rajaraman; Mark Murrie

doi:10.1039/C9CC00965E

Boosting axiality in stable high-coordinate Dy(iii) single-molecule magnets

Angelos B. Canaj, Mukesh Kumar Singh, Emma Regincos Marti, Marko Damjanovic, Claire Wilson, Oscar Cespedes, Wolfgang Wernsdorfer, Gopalan Rajaraman, Mark Murrie

Pure And Applied Chemistry

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Abstract

A new nine-coordinate, air-stable Dy(III) single-ion magnet has been successfully isolated. Our in silico studies demonstrate that through carefully modulating the ligand electronics, the axiality can be boosted to generate Ucal barriers of over 600 K

Original language	English
Pages (from-to)	5950-5953
Number of pages	4
Journal	Chemical Communications
Volume	2019
Issue number	42
DOIs	https://doi.org/10.1039/C9CC00965E
Publication status	Published - 25 May 2019

Keywords

single molecule magnets
single ion magnetism
ligand electronics

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10.1039/C9CC00965ELicence: CC BY 3.0

Canaj-etal-CC-2019-Boosting-axiality-in-stable-high-coordinateFinal published version, 2.38 MBLicence: CC BY 3.0

Cite this

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title = "Boosting axiality in stable high-coordinate Dy(iii) single-molecule magnets",

abstract = "A new nine-coordinate, air-stable Dy(III) single-ion magnet has been successfully isolated. Our in silico studies demonstrate that through carefully modulating the ligand electronics, the axiality can be boosted to generate Ucal barriers of over 600 K",

keywords = "single molecule magnets, single ion magnetism, ligand electronics",

author = "Canaj, \{Angelos B.\} and Singh, \{Mukesh Kumar\} and Marti, \{Emma Regincos\} and Marko Damjanovic and Claire Wilson and Oscar Cespedes and Wolfgang Wernsdorfer and Gopalan Rajaraman and Mark Murrie",

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language = "English",

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journal = "Chemical Communications",

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T1 - Boosting axiality in stable high-coordinate Dy(iii) single-molecule magnets

AU - Canaj, Angelos B.

AU - Singh, Mukesh Kumar

AU - Marti, Emma Regincos

AU - Damjanovic, Marko

AU - Wilson, Claire

AU - Cespedes, Oscar

AU - Wernsdorfer, Wolfgang

AU - Rajaraman, Gopalan

AU - Murrie, Mark

PY - 2019/5/25

Y1 - 2019/5/25

N2 - A new nine-coordinate, air-stable Dy(III) single-ion magnet has been successfully isolated. Our in silico studies demonstrate that through carefully modulating the ligand electronics, the axiality can be boosted to generate Ucal barriers of over 600 K

AB - A new nine-coordinate, air-stable Dy(III) single-ion magnet has been successfully isolated. Our in silico studies demonstrate that through carefully modulating the ligand electronics, the axiality can be boosted to generate Ucal barriers of over 600 K

KW - single molecule magnets

KW - single ion magnetism

KW - ligand electronics

U2 - 10.1039/C9CC00965E

DO - 10.1039/C9CC00965E

M3 - Article

SN - 1359-7345

VL - 2019

SP - 5950

EP - 5953

JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

Boosting axiality in stable high-coordinate Dy(iii) single-molecule magnets

Abstract

Keywords

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