BODIPY star-shaped molecules as solid state colour converters for visible light communications

D. A. Vithanage; P. P. Manousiadis; M. T. Sajjad; S. Rajbhandari; H. Chun; C. Orofino; D. Cortizo-Lacalle; A. L. Kanibolotsky; G. Faulkner; N. J. Findlay; D. C. O'Brien; P. J. Skabara; I. D W Samuel; G. A. Turnbull

doi:10.1063/1.4953789

BODIPY star-shaped molecules as solid state colour converters for visible light communications

D. A. Vithanage, P. P. Manousiadis, M. T. Sajjad, S. Rajbhandari, H. Chun, C. Orofino, D. Cortizo-Lacalle, A. L. Kanibolotsky, G. Faulkner, N. J. Findlay, D. C. O'Brien, P. J. Skabara, I. D W Samuel^*, G. A. Turnbull

^*Corresponding author for this work

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Abstract

In this paper, we study a family of solid-state, organic semiconductors for visible light communications. The star-shaped molecules have a boron-dipyrromethene (BODIPY) core with a range of side arm lengths which control the photophysical properties. The molecules emit red light with photoluminescence quantum yields ranging from 22% to 56%. Thin films of the most promising BODIPY molecules were used as a red colour converter for visible light communications. The film enabled colour conversion with a modulation bandwidth of 73 MHz, which is 16 times higher than that of a typical phosphor used in LED lighting systems. A data rate of 370 Mbit/s was demonstrated using On-Off keying modulation in a free space link with a distance of ∼15 cm.

Original language	English
Article number	013302
Number of pages	4
Journal	Applied Physics Letters
Volume	109
Issue number	1
DOIs	https://doi.org/10.1063/1.4953789
Publication status	Published - 4 Jul 2016

Keywords

boron-dipyrromethene
BODIPY
LED lighting systems
visible light communications
solid solutions
phosphors
organic semiconductors
light emitting diodes

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10.1063/1.4953789

Vithanage-etal-APL-2016-BODIPY-star-shaped-molecules-as-solid-state-colour-converters-for-visible-light-communicationsAccepted author manuscript, 1.05 MB

http://hdl.handle.net/10023/8910

Ultra-Parallel Visible Light Communications (UP-VLC)
Dawson, M. (Principal Investigator), Calvez, S. (Co-investigator) & Watson, I. (Co-investigator)
EPSRC (Engineering and Physical Sciences Research Council)
1/10/12 → 28/02/17
Project: Research

Data underpinning - "BODIPY star-shaped molecules as solid-state colour converters for visible light communications"
Manousiadis, P. P. (Creator), Sajjad, M. T. (Creator), Rajbhandari, S. (Creator), Chun, H. (Creator), Orofino, C. (Creator), Cortizo-Lacalle, D. (Creator), Kanibolotsky, A. L. (Creator), Faulkner, G. (Creator), Findlay, N. J. (Creator), O'Brien, D. C. (Creator), Skabara, P. J. (Creator), Samuel, I. D. W. (Creator) & Turnbull, G. A. (Creator), University of St Andrews, 27 Apr 2023
DOI: 10.17630/20163d03-6cc2-43b6-915c-d271f5220454
Dataset

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Vithanage, D. A., Manousiadis, P. P., Sajjad, M. T., Rajbhandari, S., Chun, H., Orofino, C., Cortizo-Lacalle, D., Kanibolotsky, A. L., Faulkner, G., Findlay, N. J., O'Brien, D. C., Skabara, P. J., Samuel, I. D. W., & Turnbull, G. A. (2016). BODIPY star-shaped molecules as solid state colour converters for visible light communications. Applied Physics Letters, 109(1), Article 013302. https://doi.org/10.1063/1.4953789

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title = "BODIPY star-shaped molecules as solid state colour converters for visible light communications",

abstract = "In this paper, we study a family of solid-state, organic semiconductors for visible light communications. The star-shaped molecules have a boron-dipyrromethene (BODIPY) core with a range of side arm lengths which control the photophysical properties. The molecules emit red light with photoluminescence quantum yields ranging from 22% to 56%. Thin films of the most promising BODIPY molecules were used as a red colour converter for visible light communications. The film enabled colour conversion with a modulation bandwidth of 73 MHz, which is 16 times higher than that of a typical phosphor used in LED lighting systems. A data rate of 370 Mbit/s was demonstrated using On-Off keying modulation in a free space link with a distance of ∼15 cm.",

keywords = "boron-dipyrromethene, BODIPY, LED lighting systems, visible light communications, solid solutions, phosphors, organic semiconductors, light emitting diodes",

author = "Vithanage, {D. A.} and Manousiadis, {P. P.} and Sajjad, {M. T.} and S. Rajbhandari and H. Chun and C. Orofino and D. Cortizo-Lacalle and Kanibolotsky, {A. L.} and G. Faulkner and Findlay, {N. J.} and O'Brien, {D. C.} and Skabara, {P. J.} and Samuel, {I. D W} and Turnbull, {G. A.}",

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Vithanage, DA, Manousiadis, PP, Sajjad, MT, Rajbhandari, S, Chun, H, Orofino, C, Cortizo-Lacalle, D, Kanibolotsky, AL, Faulkner, G, Findlay, NJ, O'Brien, DC, Skabara, PJ, Samuel, IDW & Turnbull, GA 2016, 'BODIPY star-shaped molecules as solid state colour converters for visible light communications', Applied Physics Letters, vol. 109, no. 1, 013302. https://doi.org/10.1063/1.4953789

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AU - Vithanage, D. A.

AU - Manousiadis, P. P.

AU - Sajjad, M. T.

AU - Rajbhandari, S.

AU - Chun, H.

AU - Orofino, C.

AU - Cortizo-Lacalle, D.

AU - Kanibolotsky, A. L.

AU - Faulkner, G.

AU - Findlay, N. J.

AU - O'Brien, D. C.

AU - Skabara, P. J.

AU - Samuel, I. D W

AU - Turnbull, G. A.

N1 - This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing.

PY - 2016/7/4

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N2 - In this paper, we study a family of solid-state, organic semiconductors for visible light communications. The star-shaped molecules have a boron-dipyrromethene (BODIPY) core with a range of side arm lengths which control the photophysical properties. The molecules emit red light with photoluminescence quantum yields ranging from 22% to 56%. Thin films of the most promising BODIPY molecules were used as a red colour converter for visible light communications. The film enabled colour conversion with a modulation bandwidth of 73 MHz, which is 16 times higher than that of a typical phosphor used in LED lighting systems. A data rate of 370 Mbit/s was demonstrated using On-Off keying modulation in a free space link with a distance of ∼15 cm.

AB - In this paper, we study a family of solid-state, organic semiconductors for visible light communications. The star-shaped molecules have a boron-dipyrromethene (BODIPY) core with a range of side arm lengths which control the photophysical properties. The molecules emit red light with photoluminescence quantum yields ranging from 22% to 56%. Thin films of the most promising BODIPY molecules were used as a red colour converter for visible light communications. The film enabled colour conversion with a modulation bandwidth of 73 MHz, which is 16 times higher than that of a typical phosphor used in LED lighting systems. A data rate of 370 Mbit/s was demonstrated using On-Off keying modulation in a free space link with a distance of ∼15 cm.

KW - boron-dipyrromethene

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KW - visible light communications

KW - solid solutions

KW - phosphors

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JO - Applied Physics Letters

JF - Applied Physics Letters

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ER -

BODIPY star-shaped molecules as solid state colour converters for visible light communications

Abstract

Keywords

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Data underpinning - "BODIPY star-shaped molecules as solid-state colour converters for visible light communications"

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