Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centered base reagent for the efficient preparation of silyl enol ethers.

William J. Kerr; Allan J. B. Watson; Douglas. Hayes

doi:10.1039/b711407a

Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centered base reagent for the efficient preparation of silyl enol ethers.

William J. Kerr, Allan J. B. Watson, Douglas. Hayes

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centered base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilizable temps.

Original language	Undefined/Unknown
Pages (from-to)	5049-5051
Number of pages	3
Journal	Chemical Communications
Issue number	47
DOIs	https://doi.org/10.1039/b711407a
Publication status	Published - 2007

Keywords

reagents
silyl enol ethers
bismesitylmagnesium

Access to Document

10.1039/b711407a

New Magnesium-based Enantioselective Deprotonation Methods; Greener General Base Strategies and the Development of a Catalytic Protocol x ref 040625
Kerr, W. (Principal Investigator)
EPSRC (Engineering and Physical Sciences Research Council)
1/09/05 → 31/01/09
Project: Research

Cite this

@article{dbeecbb2e05344729280eaf53058e763,

title = "Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centered base reagent for the efficient preparation of silyl enol ethers.",

abstract = "Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centered base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilizable temps.",

keywords = "reagents , silyl enol ethers , bismesitylmagnesium",

author = "Kerr, \{William J.\} and Watson, \{Allan J. B.\} and Douglas. Hayes",

year = "2007",

doi = "10.1039/b711407a",

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pages = "5049--5051",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "47",

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T1 - Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centered base reagent for the efficient preparation of silyl enol ethers.

AU - Kerr, William J.

AU - Watson, Allan J. B.

AU - Hayes, Douglas.

PY - 2007

Y1 - 2007

N2 - Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centered base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilizable temps.

AB - Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centered base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilizable temps.

KW - reagents

KW - silyl enol ethers

KW - bismesitylmagnesium

U2 - 10.1039/b711407a

DO - 10.1039/b711407a

M3 - Article

SN - 1359-7345

SP - 5049

EP - 5051

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centered base reagent for the efficient preparation of silyl enol ethers.

Abstract

Keywords

Access to Document

Projects

New Magnesium-based Enantioselective Deprotonation Methods; Greener General Base Strategies and the Development of a Catalytic Protocol x ref 040625

Cite this