Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(μ-cyclo­pentyl­amino-N:N)bis[dimethylaluminium(III)], [Al(CH3)2-(C5H10N)]2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement.
LanguageEnglish
Pages31-32
Number of pages1
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number1
DOIs
Publication statusPublished - Jan 2000

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Methane

Keywords

  • evolution of methane
  • dimeric species
  • cyclopentyl groups
  • crystallographic symmetry

Cite this

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title = "Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]",
abstract = "Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(μ-cyclo­pentyl­amino-N:N)bis[dimethylaluminium(III)], [Al(CH3)2-(C5H10N)]2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement.",
keywords = "evolution of methane, dimeric species, cyclopentyl groups, crystallographic symmetry",
author = "F.J. Craig and A.R. Kennedy and R.E. Mulvey",
year = "2000",
month = "1",
doi = "10.1107/S0108270199012639",
language = "English",
volume = "56",
pages = "31--32",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
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Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]. / Craig, F.J.; Kennedy, A.R.; Mulvey, R.E.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 1, 01.2000, p. 31-32.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]

AU - Craig, F.J.

AU - Kennedy, A.R.

AU - Mulvey, R.E.

PY - 2000/1

Y1 - 2000/1

N2 - Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(μ-cyclo­pentyl­amino-N:N)bis[dimethylaluminium(III)], [Al(CH3)2-(C5H10N)]2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement.

AB - Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produced the dimeric species bis(μ-cyclo­pentyl­amino-N:N)bis[dimethylaluminium(III)], [Al(CH3)2-(C5H10N)]2, which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystallographic symmetry) instead of the more common trans arrangement.

KW - evolution of methane

KW - dimeric species

KW - cyclopentyl groups

KW - crystallographic symmetry

UR - http://journals.iucr.org/c/issues/2000/01/00/gd1061/gd1061.pdf

UR - http://dx.doi.org/10.1107/S0108270199012639

U2 - 10.1107/S0108270199012639

DO - 10.1107/S0108270199012639

M3 - Article

VL - 56

SP - 31

EP - 32

JO - Acta Crystallographica Section C: Crystal Structure Communications

T2 - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 1

ER -