TY - JOUR
T1 - Bis[µ-P,P'-methylenebis(diisopropylphosphonate)-?3 O,O':O]bis[chlorolithium(I)]: A centrosymmetric dimer of lithium chloride with terminal chloride anions
AU - Henderson, K.W.
AU - Kennedy, A.R.
AU - MacDougall, D.J.
AU - Strachan, D.
PY - 2003/1/18
Y1 - 2003/1/18
N2 - The molecule of the title dimeric compound, [Li2Cl2(C13H30O6P2)2] or [LiCl{[(iPrO)2P(O)]2CH2}]2, lies about an inversion center and features tetrahedrally coordinated Li atoms. The neutral ligands each chelate to one metal center and bridge to the other center through P=O units. Unusually for lithium chloride complexes, the Cl ions are in terminal rather than bridging positions. Principal dimensions include Li-O(four-membered ring) = 1.959 (3) and 2.056 (3) î.., Li-O(phosphonate ring) = 1.929 (3) î.., and Li-Cl = 2.293 (3) î...
AB - The molecule of the title dimeric compound, [Li2Cl2(C13H30O6P2)2] or [LiCl{[(iPrO)2P(O)]2CH2}]2, lies about an inversion center and features tetrahedrally coordinated Li atoms. The neutral ligands each chelate to one metal center and bridge to the other center through P=O units. Unusually for lithium chloride complexes, the Cl ions are in terminal rather than bridging positions. Principal dimensions include Li-O(four-membered ring) = 1.959 (3) and 2.056 (3) î.., Li-O(phosphonate ring) = 1.929 (3) î.., and Li-Cl = 2.293 (3) î...
KW - dimeric compound
KW - tetrahedrally coordinated Li atoms
KW - neutral ligands
KW - lithium chloride
UR - http://www.blackwell-synergy.com/doi/full/10.1107/S0108270102022795
UR - http://dx.doi.org/10.1107/S0108270102022795
U2 - 10.1107/S0108270102022795
DO - 10.1107/S0108270102022795
M3 - Article
SN - 0108-2701
VL - 59
SP - m49-m51
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 2
ER -