Bestowing structure upon the pores of a supramolecular network

Baharan Karamzadeh; Thomas Eaton; Izabela Cebula; David Muñoz Torres; Markus Neuburger; Marcel Mayor; Manfred Buck

doi:10.1039/c4cc05934d

Bestowing structure upon the pores of a supramolecular network

Baharan Karamzadeh, Thomas Eaton, Izabela Cebula, David Muñoz Torres, Markus Neuburger, Marcel Mayor, Manfred Buck

Chemical And Process Engineering

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8 Citations (Scopus)

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Abstract

Trigonal molecules compartmentalise the pores of a honeycomb network of 3,4:9,10-tetracarboxylic diimide (PTCDI) and 1,3,5-triazine-2,4,6-triamine (melamine). Extending the 1,3,5-tri(phenylene-ethynylene)benzene core by a phenyl group allows for a well-defined accommodation of the molecule into two symmetry equivalent positions in the pore. The corresponding styryl or phenylene-ethynylene derivatives exceed the pore size and, thus, impede pore modification.

Original language	English
Pages (from-to)	14175-14178
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	91
Early online date	3 Oct 2014
DOIs	https://doi.org/10.1039/c4cc05934d
Publication status	Published - 28 Nov 2014

Keywords

trigonal molecules
supramolecular network
pore size

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10.1039/c4cc05934d

Karamzadeh-etal-CC2014-Bestowing-structure-upon-the-pores-of-a-supramolecular-networkAccepted author manuscript, 274 KB

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title = "Bestowing structure upon the pores of a supramolecular network",

abstract = "Trigonal molecules compartmentalise the pores of a honeycomb network of 3,4:9,10-tetracarboxylic diimide (PTCDI) and 1,3,5-triazine-2,4,6-triamine (melamine). Extending the 1,3,5-tri(phenylene-ethynylene)benzene core by a phenyl group allows for a well-defined accommodation of the molecule into two symmetry equivalent positions in the pore. The corresponding styryl or phenylene-ethynylene derivatives exceed the pore size and, thus, impede pore modification.",

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AU - Karamzadeh, Baharan

AU - Eaton, Thomas

AU - Cebula, Izabela

AU - Torres, David Muñoz

AU - Neuburger, Markus

AU - Mayor, Marcel

AU - Buck, Manfred

PY - 2014/11/28

Y1 - 2014/11/28

N2 - Trigonal molecules compartmentalise the pores of a honeycomb network of 3,4:9,10-tetracarboxylic diimide (PTCDI) and 1,3,5-triazine-2,4,6-triamine (melamine). Extending the 1,3,5-tri(phenylene-ethynylene)benzene core by a phenyl group allows for a well-defined accommodation of the molecule into two symmetry equivalent positions in the pore. The corresponding styryl or phenylene-ethynylene derivatives exceed the pore size and, thus, impede pore modification.

AB - Trigonal molecules compartmentalise the pores of a honeycomb network of 3,4:9,10-tetracarboxylic diimide (PTCDI) and 1,3,5-triazine-2,4,6-triamine (melamine). Extending the 1,3,5-tri(phenylene-ethynylene)benzene core by a phenyl group allows for a well-defined accommodation of the molecule into two symmetry equivalent positions in the pore. The corresponding styryl or phenylene-ethynylene derivatives exceed the pore size and, thus, impede pore modification.

KW - trigonal molecules

KW - supramolecular network

KW - pore size

UR - http://pubs.rsc.org/en/journals/journalissues/cc

U2 - 10.1039/c4cc05934d

DO - 10.1039/c4cc05934d

M3 - Article

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SN - 1359-7345

VL - 50

SP - 14175

EP - 14178

JO - Chemical Communications

JF - Chemical Communications

IS - 91

ER -

Bestowing structure upon the pores of a supramolecular network

Abstract

Keywords

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