Barriers to racemization in C₃-symmetric complexes containing the hydrotris(2-mercapto-1-ethylimidazolyl)borate (Tm^Et) ligand

Physics & Astronomy

• borates 100%
• ligands 87%
• nuclear magnetic resonance 20%
• substitutes 13%
• metal halides 11%
• energy 10%
• metals 8%
• hydrogen atoms 8%
• analogs 7%
• activation 6%
• crystal structure 6%
• density functional theory 6%
• activation energy 6%
• nitrogen 6%
• synthesis 6%
• temperature 5%
• room temperature 4%
• spectroscopy 4%
• x rays 3%

Chemical Compounds

• Borate 82%
• Ligand 38%
• Solvent 15%
• Metal 14%
• Transition State Structure 13%
• Energy Barrier 10%
• Energy 10%
• 1H NMR Spectrum 9%
• Hydrogen Atom 9%
• 1H NMR Spectroscopy 9%
• Ground State 8%
• Enantiomer 8%
• Halide 8%
• Ethyl 7%
• Reaction Activation Energy 7%
• Density Functional Theory 6%
• Nitrogen 6%
• Ambient Reaction Temperature 6%
• Crystal Structure 5%